1583294-85-2

Basic information

• Product Name: 1-chloro-1-(4-(methylthio)phenyl)silacyclobutane
• Synonyms: 1-chloro-1-(4-(methylthio)phenyl)silacyclobutane
• CAS NO: 1583294-85-2
• Molecular Weight: 228.818
• Mol File: 1583294-85-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-chloro-1-(4-(methylthio)phenyl)silacyclobutane(CAS DataBase Reference)
• NIST Chemistry Reference: 1-chloro-1-(4-(methylthio)phenyl)silacyclobutane(1583294-85-2)
• EPA Substance Registry System: 1-chloro-1-(4-(methylthio)phenyl)silacyclobutane(1583294-85-2)

Safety Data

• Hazardous Substances Data: 1583294-85-2(Hazardous Substances Data)

Upstream product

• 104-95-0 (4-bromophenyl)thioanisole 
• 2351-33-9 1,1-dichlorosilacyclobutane 

Downstream Products

• 1494347-94-2 1-(4-(methylthio)butyl)-1-(4-(methylthio)phenyl)silacyclobutane 
• 1494347-83-9 1-(4-(methylthio)phenyl)-1-phenylsilacyclobutane 

Relevant articles and documents

Silicon ring strain creates high-conductance pathways in single-molecule circuits

Here we demonstrate for the first time that strained silanes couple directly to gold electrodes in break-junction conductance measurements. We find that strained silicon molecular wires terminated by alkyl sulfide aurophiles behave effectively as single-molecule parallel circuits with competing sulfur-to-sulfur (low G) and sulfur-to-silacycle (high G) pathways. We can switch off the high conducting sulfur-to-silacycle pathway by altering the environment of the electrode surface to disable the Au-silacycle coupling. Additionally, we can switch between conductive pathways in a single molecular junction by modulating the tip-substrate electrode distance. This study provides a new molecular design to control electronics in silicon-based single molecule wires.