158407-26-2Relevant articles and documents
Palladium-catalyzed intermolecular alkene carboacylation via ester C-O bond activation
Banovetz, Haley K.,Vickerman, Kevin L.,David, Colton M.,Alkan, Melisa,Stanley, Levi M.
supporting information, p. 3507 - 3512 (2021/05/10)
We report palladium-catalyzed intermolecular carboacylation of alkenes with ester electrophiles and tetraarylborate nucleophiles. Bicyclic alkenes react with a variety of pentafluorophenyl benzoate and alkanoate esters and sodium tetraarylborates to form ketone products in ≤99% yields. These reactions occur in the absence of a directing group and demonstrate esters are competent acyl electrophiles for intermolecular alkene carboacylation reactions.
Transesterification for synthesis of carboxylates using aldehydes as acyl donors via C-H and C-O bond activations
Bao, Yong-Sheng,Chen, Chao-Yue,Huang, Zhi-Zhen
, p. 8344 - 8349,6 (2020/10/15)
A new type of transesterification between aryl, heteroaryl, alkyl N-heteroarene-2-carboxylates and various aldehydes by C-H and C-O bond activations has been developed for the synthesis of versatile carboxylates. A possible mechanism containing oxidative addition of acyl-O bond in parent ester and radical cleavage of sp2 C-H bond in aldehyde is proposed.