158556-10-6

Basic information

• Product Name: (E)-(R)-5-Bromo-1-phenyl-hexa-1,5-dien-3-ol
• Synonyms: (E)-(R)-5-Bromo-1-phenyl-hexa-1,5-dien-3-ol
• CAS NO: 158556-10-6
• Molecular Weight: 253.139
• Mol File: 158556-10-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (E)-(R)-5-Bromo-1-phenyl-hexa-1,5-dien-3-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-(R)-5-Bromo-1-phenyl-hexa-1,5-dien-3-ol(158556-10-6)
• EPA Substance Registry System: (E)-(R)-5-Bromo-1-phenyl-hexa-1,5-dien-3-ol(158556-10-6)

Safety Data

• Hazardous Substances Data: 158556-10-6(Hazardous Substances Data)

Upstream product

• 121758-21-2 2-bromo-3-(tri(n-butyl)stannyl)-1-propene 
• 13891-95-7 (1E,3R)-1-phenyl-1,5-hexadien-3-ol 
• 104-55-2 3-phenyl-propenal 
• 513-31-5 2-bromoallyl bromide 
• 14371-10-9 (E)-3-phenylpropenal 

Relevant articles and documents

Fe/Cr- and Co/Cr-mediated catalytic asymmetric 2-haloallylations of aldehydes

The first example to couple aldehydes and 3-bromo-2-halopropenes in a catalytic asymmetric manner is reported. The coupling reaction is effected by the use of a chiral sulfonamide-Cr complex (prepared in situ from 1d, CrBr3, Fe(III) or from Co(II), Et3N, and Mn), TMSCl, and 2,6-lutidine. The method reported here is operationally simple and scalable, furnishing 3-halohomoallylic alcohols with a synthetically useful level of enantiomeric excess. Copyright