158583-30-3

Basic information

• Product Name: 2-Azetidinone, 3,3-dimethyl-4-phenyl-1-(trimethylsilyl)-
• CAS NO: 158583-30-3
• Molecular Formula: C14H21NOSi
• Molecular Weight: 247.412
• Mol File: 158583-30-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2-Azetidinone, 3,3-dimethyl-4-phenyl-1-(trimethylsilyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Azetidinone, 3,3-dimethyl-4-phenyl-1-(trimethylsilyl)-(158583-30-3)
• EPA Substance Registry System: 2-Azetidinone, 3,3-dimethyl-4-phenyl-1-(trimethylsilyl)-(158583-30-3)

Safety Data

• Hazardous Substances Data: 158583-30-3(Hazardous Substances Data)

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 7486-93-3 3,3-dimethyl-4-phenylazetidin-2-one 
• 999-97-3 1,1,1,3,3,3-hexamethyl-disilazane 
• 17599-61-0 N-benzylidene-1,1,1-trimethylsilanamine 
• 97-62-1 Ethyl isobutyrate 

Downstream Products

• 176172-41-1 2-(3,3-dimethyl-2-oxo-4-phenylazetidin-1-yl)-1,3,2-dioxaphosphorinane 

Relevant articles and documents

Ester-imine condensation mediated by potassium tert-butoxide: Synthesis of β-lactams and 3,4-dihydropyridin-2-ones

The utility of the weak base potassium tert-butoxide has been successfully demonstrated in the synthesis of β-lactams and 3,4-dihydropyridin-2-ones starting from esters and imines.

N-Phosphorylated lactams 2. Reversible phosphorylation of silyllactams

The phosphorylation of N-trimethylsilyllactams by phosphorus(III) acid chlorides results in corresponding N-phosphinolactams in high yields. The derivatives thus obtained have been used in the synthesis of N-phosphoryl- and N-thiophosphoryllactams. The reversibility of the reaction of phosphinolactams has been established. - Keywords: N-trimethylsilyllactams; reversible phosphorylation; N-phosphoryllactams, synthesis.