15980-15-1Relevant articles and documents
Reactions of bielectrophiles (ClCH2CH2)2Y with sulfur in basic reducing systems
Korchevin,Russavskaya,Alekminskaya,Deryagina
, p. 240 - 243 (2002)
A simple procedure was developed for preparing bis(β-mercaptoethyl) ether and bis(β-mecraptoethyl) sulfide from commercially available chemicals: elemental sulfur, alkali, and bis(β-chloroethyl) ether or sulfide, based on thiylation with elemental sulfur of these substrates in the aqueous system hydrazine hydrate-alkali, with initial formation of the corresponding polysulfide polymers (thiokols). Their reduction with the system hydrazine hydrate-alkali, followed by acidification of dithiolate anions, yields the corresponding dithiols. Thiokols based on bis(β-chloroethyl) ether are soluble in organic solvents; they were studied by 1H NMR.
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Georgieff,Dupre
, p. 1104,1107 (1959)
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Destruction of chemical warfare agent simulants by air and moisture stable metal NHC complexes
Weetman, Catherine,Notman, Stuart,Arnold, Polly L.
supporting information, p. 2568 - 2574 (2018/02/28)
The cooperative effect of both NHC and metal centre has been found to destroy chemical warfare agent (CWA) simulants. Choice of both the metal and NHC is key to these transformations as simple, monodentate N-heterocyclic carbenes in combination with silver or vanadium can promote stoichiometric destruction, whilst bidentate, aryloxide-tethered NHC complexes of silver and alkali metals promote breakdown under mild heating. Iron-NHC complexes generated in situ are competent catalysts for the destruction of each of the three targetted CWA simulants.
Metal ferrite nanoparticles: Synthesis, characterization, and studies on decontamination of sulfur mustard
Praveen Kumar,Prasad,Ramacharyulu,Singh, Beer,Anchal Roy
, p. 833 - 840 (2016/09/28)
Mg, Ca, Mn, Co, Ni, Cu, Zn, Mn-Zn, and Co-Zn metal ferrite and mixed metal ferrite nanoparticles were synthesized by co-precipitation method and were characterized by using transmission electron microscopy, X-ray diffraction, and nitrogen adsorption techn