16002-63-4

Basic information

• Product Name: PHENYLMAGNESIUM IODIDE
• Synonyms: PHENYLMAGNESIUM IODIDE;42%inethyletherca.2mol/L;Phenylmagnesium Iodide (42% in Ethyl Ether, ca. 2mol/L);Phenyliodomagnesium;PhenylMagnesiuM Iodide PhenylMagnesiuM Iodide (ca. 42% in Ethyl Ether, ca. 2Mol/L);Phenylmagnesium iodide, 0.50 M in THF
• CAS NO: 16002-63-4
• Molecular Formula: C₆H₅IMg
• Molecular Weight: 228.31
• Product Categories: Classes of Metal Compounds;Grignard Reagents;Grignard Reagents & Alkyl Metals;Mg (Magnesium) Compounds;Synthetic Organic Chemistry;Typical Metal Compounds;Pharm intermediate
• Mol File: 16002-63-4.mol
• Article Data: 6

Chemical Properties

• Appearance: /
• CAS DataBase Reference: PHENYLMAGNESIUM IODIDE(CAS DataBase Reference)
• NIST Chemistry Reference: PHENYLMAGNESIUM IODIDE(16002-63-4)
• EPA Substance Registry System: PHENYLMAGNESIUM IODIDE(16002-63-4)

Safety Data

• RIDADR: UN 2924 3/8/PG I
• HazardClass: 3/8
• PackingGroup: I
• Hazardous Substances Data: 16002-63-4(Hazardous Substances Data)

Usage

General Description

Phenylmagnesium iodide is a chemical compound with the formula C6H5MgI. It is a Grignard reagent, which means it is a highly reactive and versatile organometallic compound that is commonly used in organic synthesis. It is typically prepared by reacting bromobenzene with magnesium in the presence of an iodine catalyst. Phenylmagnesium iodide is used as a strong nucleophile in the formation of carbon-carbon bonds, particularly in the formation of aryl-aryl, aryl-alkyl, and aryl-heteroatom bonds. It is also used in the synthesis of various pharmaceuticals, natural products, and other organic compounds. Due to its reactivity, phenylmagnesium iodide is typically handled and stored under anhydrous and inert conditions.

InChI:InChI=1/C6H5.HI.Mg/c1-2-4-6-5-3-1;;/h1-5H;1H;/q;;+1/p-1/rC6H5IMg/c7-8-6-4-2-1-3-5-6/h1-5H

Upstream product

• 591-50-4 iodobenzene 
• 60-29-7 diethyl ether 
• 3124-01-4 hexaphenyl diplumbane 
• 71-43-2 benzene 

Downstream Products

• 29909-72-6 3-Phenylbenzofuran 
• 100-52-7 benzaldehyde 
• 14385-52-5 5-methyl-3-phenyl-2,3-benzofuran 
• 92-52-4 biphenyl 
• 139-66-2 diphenyl sulfide 
• 618-41-7 Benzenesulfinic acid 
• 882-33-7 diphenyldisulfane 
• 76-84-6 triphenylmethyl alcohol 
• 5333-62-0 benzyl trityl ether 
• 65-85-0 benzoic acid 
• 100-51-6 benzyl alcohol 
• 108-95-2 phenol 
• 6201-08-7 10,10'-Dibenzoyl-9,10,9',10'-tetrahydro-[9,9']bianthryl 
• 119-53-9 2-hydroxy-2-phenylacetophenone 

Relevant articles and documents

An N-Fluorinated Imide for Practical Catalytic Imidations

Catalytic imidation using NFSI as the nitrogen source has become an emerging tool for oxidative carbon-nitrogen bond formation. However, the less than ideal benzenesulfonimide moiety is incorporated into products, severely detracting its synthetic value.

PLATINUM COMPLEXES

The invention aims at providing platinum complexes useful as materials for light emitting devices and extremely excellent in heat stability, luminous characteristics, and luminous efficiency, and a process for effective preparation thereof. The invention relates to platinum complexes represented by the general formula [1]: wherein any two of A, B and C are each independently an optionally substituted nitrogenous aromatic heterocyclic group and the other is optionally substituted aryl or optionally substituted heteroaryl; and Y is halogeno or an optionally substituted aryl or heteroaryl group which is bonded either directly or through oxygen (-O-) or sulfur (-S-) (with the proviso that when the adjacent two rings are nitrogenous aromatic heterocyclic groups, the cases wherein Y is chloro are excepted, while when the nonadjacent two rings are nitrogenous aromatic heterocyclic groups, the cases wherein Y is not halogeno are excepted).

Kinetics and Thermodynamics of Oxidation of Magnesium with Phenyl Halides in Benzene in the Presence of Diethyl Ether

The equilibrium constants and the enthalpies and entropies of adsorption of phenyl chloride and phenyl iodide on the surface of magnesium during oxidation in benzene were determined. The reaction scheme explaining acceleration of conversion and increase in the fraction of products of the Wuertz reaction with increasing concentration of oxidant was suggested.