16004-75-4

Basic information

• Product Name: 1,3,5,7-TETRAPHENYLADAMANTANE
• Synonyms: 1,3,5,7-TETRAPHENYLADAMANTANE;Tricyclo[3.3.1.13,7]decane, 1,3,5,7-tetraphenyl-
• CAS NO: 16004-75-4
• Molecular Formula: C₃₄H₃₂
• Molecular Weight: 440.62
• Mol File: 16004-75-4.mol
• Article Data: 18

Chemical Properties

• Melting Point: 403-404 °C
• Boiling Point: 575.5±50.0 °C(Predicted)
• Appearance: /
• Density: 1.174±0.06 g/cm3(Predicted)
• CAS DataBase Reference: 1,3,5,7-TETRAPHENYLADAMANTANE(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3,5,7-TETRAPHENYLADAMANTANE(16004-75-4)
• EPA Substance Registry System: 1,3,5,7-TETRAPHENYLADAMANTANE(16004-75-4)

Safety Data

• Hazardous Substances Data: 16004-75-4(Hazardous Substances Data)

Usage

Uses

1,3,5,7-Tetraphenyladamantane is a useful synthetic intermediate in the preparation of nanoporous amide networks (NAN), which are used to selectively capture CO2 from anthropogenic emissions.

InChI:InChI=1S/C34H32/c1-5-13-27(14-6-1)31-21-32(28-15-7-2-8-16-28)24-33(22-31,29-17-9-3-10-18-29)26-34(23-31,25-32)30-19-11-4-12-20-30/h1-20H,21-26H2

Upstream product

• 7314-86-5 1,3,5,7-tetrabromoadamantane 
• 71-43-2 benzene 
• 281-23-2 adamantane 
• 768-90-1 1-Adamantyl bromide 

Downstream Products

• 75534-58-6 1,3,5,7-tetrakis(hydroxymethyl)adamantane 
• 158562-40-4 1,3,5,7-tetrakis-(4-aminophenyl)adamantane 
• 1029302-61-1 1,3,5,7-tetrakis(4-methoxyphenyl)adamantane 
• 144970-32-1 1,3,5,7-tetrakis(4-ethinylphenyl)adamantane 
• 1425940-31-3 1,3,5,7-tetrakis(4-(1,2,3,4-tetrazol-5-yl)phenyl)adamantane 
• 167013-18-5 1,3,5,7-tetrakis-(4-nitrophenyl)adamantane 
• 100884-80-8 adamantane-1,3,5,7-tetracarboxylic acid 
• 144970-30-9 1,3,5,7-tetrakis(4-iodophenyl)adamantane 
• 154694-31-2 ((adamantane-1,3,5,7-tetrayl)tetra(phen-4- yl))tetracarboxylic acid 
• 167013-23-2 1,3,5,7-tetrakis-(4-cyanophenyl)adamantane 
• 144970-36-5 1,3,5,7-tetrakis(4-bromophenyl)adamantane 
• 16080-28-7 1,3,5,7-Tetracyclohexyl-adamantan 

Relevant articles and documents

Novel sulfonate-containing halogen-free flame-retardants: Effect of ternary and quaternary sulfonates centered on adamantane on the properties of polycarbonate composites

In order to find a more environmentally friendly flame retardant, we have designed a novel halogen-free flame-retardant (FR) system consisting of ternary and quaternary sulfonates centered on adamantane. They are named 1,3,5-tri(phenyl-4-sodium sulfonate)adamantane (AS3) and 1,3,5,7-tetrakis(phenyl-4-sodium sulfonate)adamantane (AS4), respectively. Both kinds of FRs were synthesized and compounded with polycarbonate (PC) to study their effects on the properties of PC composites. The results show that the new FR system can improve PC flame retardancy efficiently, and has mechanical strength advantages as well. The PC composites with only 0.1 wt% AS3 or 0.08 wt% AS4 can pass vertical burning tests (UL-94) V-0 level, with increasing the value of limiting oxygen index (LOI) to 31.2% or 32.3%. Moreover, they can maintain ideal mechanical properties compared to neat PC simultaneously. Finally, the flame retardant mechanism of this system was verified via thermal analysis, morphology and chemical structure analysis of the char residues.

Regioselective Synthesis of meta-Tetraaryl-Substituted Adamantane Derivatives and Evaluation of Their White Light Emission

New meta-substituted tetraaryl adamantane derivatives were synthesized through one-step Friedel-Crafts adamantylation by using AlCl3 in combination with t-butyl bromide. The products exhibit improved (over tetraphenyl adamantane) highly directional white-light emission upon irradiation with a continuous wave (CW) laser diode.

Azo-linked porous organic polymers: Robust and time-efficient synthesis: Via NaBH4-mediated reductive homocoupling on polynitro monomers and adsorption capacity towards aniline in water

Time-efficient synthetic methods of porous organic polymers are searched in order to extend the applications of these materials. In this work, we show a robust and time-efficient synthetic method of azo-linked porous organic polymers named Azo-POPs based on a NaBH4-mediated reductive coupling polymerization on well-known polynitro monomers. Azo-POPs were found to have a high Brunauer-Emmett-Teller (BET) surface area and potential for aniline adsorption. Interestingly, Azo-POP-1 showed adsorption capacity towards aniline as high as 1059.68 mg g-1 at 293 K, which surpassed that of adsorbent materials reported in the literature.