1604-34-8Relevant articles and documents
KINETIC PRINCIPLES OF THE HYDROGENATION OF 6,10-DIMETHYL-UNDECA-3,5,9-TRIEN-2-ONE ON RANEY NICKEL
Sul'man, E. M.,Popov, O. S.,Samokhvalov, G. I.
, p. 61 - 63 (1988)
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KINETIC REGULARITIES OF HYDROGENATION OF 6,10-DIMETHYL-3,5,9-UNDECATRIEN-2-ONE AT ELEVATED HYDROGEN PRESSURE. III. HYDROGENATION IN OPEN SYSYEM
Sul'man, E. M.,Popov, O. S.,Sannikov, O. B.,Samokhvalov, G. I.,Ankudinova, T. V.,et al.
, p. 427 - 429 (1986)
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SELECTIVE HYDROGENATION OF 6,10-DIMETHYLUNDECA-3,5,9-TRIEN-2-ONE ON RANEY NICKEL CATALYST
Sul'man, E. M.,Popov, O. S.
, p. 799 - 802 (1987)
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PROCESS OF ASYMMETRIC HYDROGENATION OF KETALS AND ACETALS
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Page/Page column 55; 60, (2014/07/08)
The present invention relates to a process of the asymmetric hydrogenation of a ketal of an unsaturated ketone or an acetal of an unsaturated aldehyde by molecular hydrogen in the presence of at least one chiral iridium complex. This process yields chiral compounds in a very efficient way and is very advantageous in that the amount of iridium complex can be remarkably reduced.
Cyclization of N,N-diethylgeranylamine N-oxide in one-pot operation: preparation of cyclic terpenoid-aroma chemicals
Takabe, Kunihiko,Yamada, Takashi,Miyamoto, Takenori,Mase, Nobuyuki
scheme or table, p. 6016 - 6018 (2009/04/11)
Acid promoted cyclization of the geranylamine N-oxide (E)-4 followed by base-catalyzed intramolecular aldol condensation afforded 1-acetyl-4,4-dimethyl-1-cyclohexene (7) in one-pot operation. Reduction of 7, which possess strong fruity odor, followed by lipase-catalyzed kinetic resolution furnished the acetate (R)-26 (>49.9% yield, >99% ee) and the recovered alcohol (S)-25 (>49.9% yield, >99% ee, herbal odor).