1609451-14-0

Basic information

• Product Name: (RuPhos)Pd(COCF₃)(OCOCF₃)
• CAS NO: 1609451-14-0
• Molecular Weight: 783.097
• Mol File: 1609451-14-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (RuPhos)Pd(COCF₃)(OCOCF₃)(CAS DataBase Reference)
• NIST Chemistry Reference: (RuPhos)Pd(COCF₃)(OCOCF₃)(1609451-14-0)
• EPA Substance Registry System: (RuPhos)Pd(COCF₃)(OCOCF₃)(1609451-14-0)

Safety Data

• Hazardous Substances Data: 1609451-14-0(Hazardous Substances Data)

Upstream product

• 787618-22-8 ruphos 
• 1271-03-0 allyl(cyclopentadiene)palladium(II) 
• 14533-84-7 pentafluorophenyl trifloroacetate 

Downstream Products

• 1609451-23-1 (RuPhos)Pd(CF₃)(o-C₆H₄CH₃) 
• 1609451-18-4 (RuPhos)Pd(CF₃)(OCOCF₃) 
• 1609451-22-0 (RuPhos)Pd(CF₃)(Ph) 

Relevant articles and documents

Catalytic cycle for palladium-catalyzed decarbonylative trifluoromethylation using trifluoroacetic esters as the CF3 source

This paper demonstrates a catalytic cycle for Pd-catalyzed decarbonylative trifluoromethylation using trifluoroacetic esters as CF3 sources. The proposed cycle consists of four elementary steps: (1) oxidative addition of a trifluoroacetic ester to Pd0, (2) CO deinsertion from the resulting trifluoroacyl PdII complex, (3) transmetalation of a zinc aryl to PdII, and (4) aryl-CF3 bond-forming reductive elimination. The use of RuPhos as the supporting ligand enables each of these steps to proceed under mild conditions (3 sources.