161196-23-2

Basic information

• Product Name: (THIOXO-1,3-OXATHIOLAN-5-YL)METHYL METHACYLATE
• Synonyms: 2-THIOXO-1,3-OXATHIOLAN-5-YLMETHYL METHACRYLATE;5-(METHACRYLOYLOXY)METHYL-1,3-OXATHIOLANE-2-THIONE;(THIOXO-1,3-OXATHIOLAN-5-YL)METHYL METHACYRLATE;(THIOXO-1,3-OXATHIOLAN-5-YL)METHYL METHACYLATE
• CAS NO: 161196-23-2
• Molecular Formula: C8H10O3S2
• Molecular Weight: 218.29
• Product Categories: Sulfur Compounds (for Synthesis);Synthetic Organic Chemistry
• Mol File: 161196-23-2.mol
• Article Data: 6

Chemical Properties

• Boiling Point: 317.7°C at 760 mmHg
• Flash Point: 145.9°C
• Appearance: /
• Density: 1.3g/cm³
• Vapor Pressure: 0.000379mmHg at 25°C
• Refractive Index: 1.575
• Storage Temp.: Refrigerator
• CAS DataBase Reference: (THIOXO-1,3-OXATHIOLAN-5-YL)METHYL METHACYLATE(CAS DataBase Reference)
• NIST Chemistry Reference: (THIOXO-1,3-OXATHIOLAN-5-YL)METHYL METHACYLATE(161196-23-2)
• EPA Substance Registry System: (THIOXO-1,3-OXATHIOLAN-5-YL)METHYL METHACYLATE(161196-23-2)

Safety Data

• Statements: 20/21/22
• Safety Statements: 36/37/39-45
• Hazardous Substances Data: 161196-23-2(Hazardous Substances Data)

Usage

General Description

"(THIOXO-1,3-OXATHIOLAN-5-YL)METHYL METHACYLATE" is a chemical compound with the molecular formula C8H10O3S2. It is used as a monomer in the production of polymers and copolymers. (THIOXO-1,3-OXATHIOLAN-5-YL)METHYL METHACYLATE has potential applications in various industries, including adhesives, coatings, and plastics. It contains a thioxo oxide moiety, which gives it unique properties that make it suitable for use in a wide range of products. However, (THIOXO-1,3-OXATHIOLAN-5-YL)METHYL METHACYLATE should be handled with caution due to its potential hazards and toxicity.

InChI:InChI=1/C8H10O3S2/c1-5(2)7(9)10-3-6-4-13-8(12)11-6/h6H,1,3-4H2,2H3

Upstream product

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Relevant articles and documents

Regio- and Stereoselective Synthesis of Dithiocarbonates under Ambient and Solvent-Free Conditions

Herein, we report on the utilization of readily available lithium tert-butoxide as an efficient catalyst for the addition of carbon disulfide to terminal and internal epoxides under ambient conditions. Notably, the reaction proceeds regio- and stereoselectively. By applying the optimized conditions, 14 terminal and internal epoxides were converted. The desired cyclic dithiocarbonates were isolated in yields up to 95 % after simple filtration over silica. NMR spectroscopy experiments to identify the mode of activation were performed, and they indicated activation of carbon disulfide by the catalyst. The reaction of cis-2,3-butyleneoxide gave only the trans-dithiocarbonate, whereas the conversion of (R)-propylen oxide gave the respective thiocarbonate stereoselectively as one enantiomer (>99 % ee) in 87 % yield.

Organocatalytic one-pot synthesis of functionalized 1,3-oxathiolanes and 1,3-thiazolidines

An efficient organocatalytic approach for the synthesis of 1,3-oxathiolanes and 1,3-thiazolidines is reported. In this methodology, conjugated base of nitromethane was employed as a potential organocatalyst to promote cyclization reaction between strained

Cyclic dithiocarbonates, their preparation and application

The present invention relates to cyclic 5-membered ring dithiocarbonate compounds of the general formula wherein, in the formula, R1, R2, and R3 are the same or different, each of which denotes hydrogen or a C1 to C4 strai