1613027-56-7Relevant articles and documents
Palladium-Catalyzed Decarboxylative Synthesis of Arylamines
Dai, Qipu,Li, Peihe,Ma, Nuannuan,Hu, Changwen
, p. 5560 - 5563 (2016/11/17)
A novel approach has been developed for the synthesis of arylamines via the palladium-catalyzed intramolecular decarboxylative coupling (IDC) of aroyloxycarbamates, obtained in situ by reacting aryl carboxylic acids with hydroxycarbamates. The reaction offers facile access to structurally diverse arylamines with the site-specific formation of the C(sp2)-N bond under mild conditions.