16450-38-7Relevant articles and documents
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McCasland,Proskow
, p. 122,125 (1957)
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Preparation method of spiro cyclic quaternary ammonium salt
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Paragraph 0131; 0132, (2016/10/17)
The invention discloses a preparation method of a spiro cyclic quaternary ammonium salt, which comprises the following steps of: in the water, a nucleophilic substitution reaction is carried out on a compound 3 and ammonia to generate the spiro cyclic quaternary ammonium 2. The reaction temperature is between 40 DEG C and 200 DEG C. The preparation method of the invention has the advantages that raw materials are cheap and low toxic, the metal ion content in products is low and the purity is high, and the operation is simple. The preparation method of the spiro cyclic quaternary ammonium salt is suitable for industrial production.
Method for purifying quaternary ammonium systems with high purity
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Paragraph 0048-0051, (2016/10/10)
PURPOSE: A purification method of a quaternary ammonium salt is provided to obtain high purity quaternary ammonium salt by a simple and low costs process. CONSTITUTION: A purification method of a quaternary ammonium includes a step of dissolving a quaternary ammonium salt represented by chemical formula 1, in an organic solvent, and filtering the solution. In chemical formula 1, each of N1, N2, N3, and N4 is an integer from 0-6; each of X11, X12, X13, and X14 is CH or CH2; a part or a whole part of the hydrogen is substituted by C1-6 alkyl, or is C3-8 cyclic or heterocyclic; each of X21 and X22 is X11, X12, X13, X14, NH, O, or S; each of X31 and X32 is X11, X12, X13, X14, H, C1-6 alkoxy, or C1-6 alkenyl; each of X31 and X32 is X11, X12, X13, X14, H, C1-6 alkoxy or C1-6 alkenyl; and A is an anion of halide.