16491-63-7

Basic information

• Product Name: allyl cyclohexanecarboxylate
• Synonyms: allyl cyclohexanecarboxylate;Cyclohexanecarboxylic acid 2-propenyl ester;Cyclohexanecarboxylic acid allyl ester;Ai3-19784;Einecs 240-556-3
• CAS NO: 16491-63-7
• Molecular Formula: C₁₀H₁₆O₂
• Molecular Weight: 168.23284
• EINECS: 240-556-3
• Mol File: 16491-63-7.mol
• Article Data: 12

Chemical Properties

• Boiling Point: 228.3°C at 760 mmHg
• Flash Point: 82.9°C
• Appearance: /
• Density: 0.977g/cm³
• Vapor Pressure: 0.0739mmHg at 25°C
• Refractive Index: 1.465
• CAS DataBase Reference: allyl cyclohexanecarboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: allyl cyclohexanecarboxylate(16491-63-7)
• EPA Substance Registry System: allyl cyclohexanecarboxylate(16491-63-7)

Safety Data

• Hazardous Substances Data: 16491-63-7(Hazardous Substances Data)

Usage

General Description

Allyl cyclohexanecarboxylate is an organic compound with the chemical formula C10H16O2. It is commonly used in the fragrance and flavor industry due to its sweet, fruity, and floral aroma. The chemical is often used in the production of perfumes, soaps, and other personal care products. It is also used as a flavoring agent in food and beverages. Allyl cyclohexanecarboxylate is a clear, colorless liquid with a low volatility and a high boiling point, making it suitable for a wide range of applications. While it is generally considered safe for use in consumer products, it should be handled and stored with care due to its potential irritant and sensitizing properties.

InChI:InChI=1/C10H16O2/c1-2-8-12-10(11)9-6-4-3-5-7-9/h2,9H,1,3-8H2

Upstream product

• 107-18-6 allyl alcohol 
• 2719-27-9 cyclohexanylcarbonyl chloride 
• 98-89-5 Cyclohexanecarboxylic acid 
• 108233-78-9 diallyl 1,1-cyclohexanedicarboxylate 
• 24850-33-7 allyltributylstanane 
• 357604-43-4 prop-2-yn-1-yl cyclohexanecarboxylate 
• 72963-31-6 dimethyl 1,1-cyclohexanedicarboxylate 
• 1196662-63-1 allyl 1-bromocyclohexanecarboxylate 
• 14593-43-2 benzyl allyl ether 
• 60718-45-8 1-cyclohexanecarbonyl-1H-imidazole 
• 107-05-1 3-chloroprop-1-ene 
• 29548-87-6 1-bromocyclohexanecarboxylic acid chloride 
• 106-95-6 allyl bromide 
• 70659-83-5 N-allylcyclohexanecarboxamide 

Downstream Products

• 4404-61-9 cyclohexyldiphenylmethanol 
• 98-89-5 Cyclohexanecarboxylic acid 
• 57013-02-2 (Z)-1,2-dicyclohexylethylene 
• 123-38-6 propionaldehyde 
• 1384266-46-9 (Z)-prop-1-enyl cyclohexanecarboxylate 
• 1384266-45-8 (E)-prop-1-enyl cyclohexanecarboxylate 

Relevant articles and documents

Enantioselective Three-Component Fluoroalkylarylation of Unactivated Olefins through Nickel-Catalyzed Cross-Electrophile Coupling

A nickel-catalyzed, enantioselective, three-component fluoroalkylarylation of unactivated alkenes with aryl halides and perfluoroalkyl iodides has been described. This cross-electrophile coupling protocol utilizes a chiral nickel/BiOx system as well as a pendant chelating group to facilitate the challenging three-component, asymmetric difunctionalization of unactivated alkenes, providing direct access to valuable chiral β-fluoroalkyl arylalkanes with high efficiency and excellent enantioselectivity. The mild conditions allow for a broad substrate scope as well as good functional group toleration.

Safe Removal of the Allyl Protecting Groups of Allyl Esters using a Recyclable, Low-Leaching and Ligand-Free Palladium Nanoparticle Catalyst

A safe, facile and low-leaching (up to 0.04ppm) method has been developed for the removal of allyl, prenyl and benzyl protecting groups from the corresponding esters, using a sulfur-modified gold-supported palladium (SAPd) nanoparticle catalyst, which is known to be non-flammable. The catalyst itself was found to be recyclable and the reaction appeared to proceed on the surface of the SAPd.

Use of diethoxymethane as a solvent for phase-transfer esterification of carboxylic acids

The esterification of carboxylic acids with selected primary alkyl halides in diethoxymethane (DEM) utilizing solid-liquid phase-transfer catalysis has been studied. The use of DEM as the solvent simplifies the process in that a single solvent can be used for both reaction and workup.