164921-70-4Relevant articles and documents
Reaction of methyl 4,5-epoxy-(2E)-pentenoate with arylcopper reagents
Nagumo,Irie,Akita
, p. 675 - 680 (2007/10/03)
The reaction of methyl 4,5-epoxy-(2E)-pentenoate (1) with various arylcopper reagents was studied. Basically, all arylcopper reagents react with 1 in SN2 fashion. However, addition of BF3 causes reversal of the regioselectivity, which can be ra
Reaction of methyl 4,5-epoxy-(2E)-pentenoate with arenes. I. A facile synthesis of 4-aryl-5-hydroxy-(2E)-pentenoate derivatives
Ono,Todoriki,Yamamoto,Akita
, p. 1590 - 1595 (2007/10/02)
The reactivity of methyl 4,5-epoxy-(2E)-pentenoate (2) toward various aromatic nucleophiles in the presence of boron trifluoride etherate was examined. When benzene derivatives possessing an electron-donating substituent were employed, meta-substituted be