16696-68-7Relevant articles and documents
Reactions of 1,3-Epithionaphtho5,6λ5>thiadiphosphinine-1,3-dithione; the Preparation and X-ray Structure of NpP(S)(SMe)SP(S)(OMe), the first C3P2S Ring
Eleftheriou, Maria-Elena,Novosad, Josef,Williams, David J.,Woollins, J. Derek
, p. 116 - 117 (1991)
NpP2S4 1 (Np = C10H6, naphthalene-1,8-diyl) reacts with carbonyl groups to give thiocarbonyls whilst refluxing 1 in methanol results in cleavage of one of the P-S-P bridges and formation of the new heterocycle 3 which contains a C3P2S ring with the phosph
Stereospecific Reactions of Donor–Acceptor Cyclopropanes with Thioketones: Access to Highly Substituted Tetrahydrothiophenes
Augustin, André U.,Sensse, Maximilian,Jones, Peter G.,Werz, Daniel B.
supporting information, p. 14293 - 14296 (2017/10/31)
Lewis-acid-catalyzed reactions of 2-substituted cyclopropane 1,1-dicarboxylates with thioketones are described. Highly substituted tetrahydrothiophenes with two adjacent quaternary carbon atoms were obtained in a stereospecific manner under mild conditions and in high yield when using AlCl3 as Lewis acid. Moreover, an intramolecular approach was successfully implemented to gain access to sulfur-bridged [n.2.1] bicyclic ring systems. Conversion of selenoketones, the heavier analogues, under similar conditions resulted in the formation of various tetrahydroselenophenes.
METHODS FOR TREATING OR PREVENTING AN INFLAMMATORY OR METABOLIC CONDITION OR INHIBITING JNK
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, (2008/06/13)
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