167111-53-7

Basic information

• Product Name: Cr(CO)4((C₆H₅)2PCH(Au(P(C₆H₅)3))P(C₆H₅)2)
• CAS NO: 167111-53-7
• Molecular Weight: 1006.68
• Mol File: 167111-53-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Cr(CO)4((C₆H₅)2PCH(Au(P(C₆H₅)3))P(C₆H₅)2)(CAS DataBase Reference)
• NIST Chemistry Reference: Cr(CO)4((C₆H₅)2PCH(Au(P(C₆H₅)3))P(C₆H₅)2)(167111-53-7)
• EPA Substance Registry System: Cr(CO)4((C₆H₅)2PCH(Au(P(C₆H₅)3))P(C₆H₅)2)(167111-53-7)

Safety Data

• Hazardous Substances Data: 167111-53-7(Hazardous Substances Data)

Upstream product

• 109-72-8 n-butyllithium 
• 14243-64-2 (triphenylphosphine)gold(I) chloride 
• 16743-46-7 tetracarbonyl-bis(diphenylphosphino)methane-chromium(0) 

Relevant articles and documents

Organomercuration of the carbanion derived from (M=Cr, Mo or W). Crystal and molecular structure of >

The carbanions resulting from the deprotonation by n-BuLi of compounds of the type (M=Cr, Mo or W) are readily organomercurated by RHgCl to give neutral complexes of the type >.The X-ray crystal structure of the complex with M=Cr and R=Me has been determined, and reveals intermolecular C-H...O hydrogen bonding interactions to carbonyl oxygen acceptor atoms and a weak secondary intermolecular interaction between a carbonyl oxygen and the mercury atom.Keywords: Chromium; Molybdenum; Tungsten; Carbonyl; Bis(diphenylphosphino)methane; Carbanions