16736-42-8Relevant articles and documents
Porri et al.
, p. 4187 (1965)
An Efficient Electrochemical Coupling of Allylic Halides by Using a Copper Anode
Tokuda, Masao,Endate, Kazuhiro,Suginome, Hiroshi
, p. 945 - 948 (1988)
A new electrolytic method for an efficient coupling of allylic halides by the use of a copper anode and a platinum cathode in the precence of sodium iodide is described.A method which avoids a loss of the copper anode owing to dissolution is also described.
Pines
, p. 309,311 (1974)
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Webb,Borcherdt
, p. 2654 (1951)
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Stevens,Spalding
, p. 1687,1691 (1949)
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Catalyst-free suzuki-type coupling of allylic bromides with arylboronic acids
Scrivanti, Alberto,Beghetto, Valentina,Bertoldini, Matteo,Matteoli, Ugo
supporting information; experimental part, p. 264 - 268 (2012/02/04)
The coupling of arylboronic acids with electron-rich allylic bromides is accomplished in the absence of any transition-metal catalyst through conventional heating. The reaction is completely regioselective, affording only the α-coupled product, and can be carried out under mild aerobic conditions in an organic solvent; the presence of a base is required. Copyright
- the Wet Chemical Route to a Highly Reactive Titanium Hydride
Becker, Beate,Bogdanovic, Borislav
, p. 476 - 482 (2007/10/02)
The reaction between catalytically prepared magnesium hydride (MgH2*) and in a molar ratio of 1.5:1 in THF yields a highly pyrophoric, X-ray amorphous titanium hydride precipitate with the composition (2).This novel titanium hydride precipitate with the composition (2).This novel titanium hydride has been characterized through hydrolysis and iodolysis, as well as through thermolysis to Ti* and H2 in the solid state and in organic solvents. 2 is slightly soluble in THF and proves itself as an active reagent in a variety of reactions. - Keywords: Magnesium Hydride, Titanium Hydride, McMurry-Reaction, Titanium