16825-71-1Relevant articles and documents
Mild and efficient synthesis of iodylarenes using Oxone as oxidant
Soldatova, Natalia,Postnikov, Pavel,Troyan, Anna A.,Yoshimura, Akira,Yusubov, Mekhman S.,Zhdankin, Viktor V.
supporting information, p. 4254 - 4256 (2016/08/25)
Mild and efficient method for the preparation of iodylarenes by oxidation of iodoarenes with Oxone in aqueous acetonitrile at room temperature is described. This new procedure allows the preparation of various iodylarenes with electron-donating or electron-withdrawing substituents in the aromatic ring including the previously unknown 1,2-diiodylbenzene.
Simple anf Efficient Palladium-Catalyzed Carbonylation of Iodoxyarenes in Water under Mild Conditions
Grushin, Vladimir V.,Alper, Hovard
, p. 4794 - 4795 (2007/10/02)
Iodoxyarenes (ArIO2) readily react with CO (1 atm) in water, in the presence of Na2 (0.1percent) and Na2CO3 at 40-50 deg C, to give the corresponding carboxylic acids, ArCOOH, in 55-89percent isolated yield.Particulary attractive features of the reaction are that, unlike most iodoarenes, ArIO2 can be carbonylated in aqueous media without any organic solvents, due to their solubility in water and high reactivity.
