16913-62-5

Basic information

• Product Name: Carbamodithioic acid, dimethyl-, 4-methylphenyl ester
• CAS NO: 16913-62-5
• Molecular Formula: C10H13NS2
• Molecular Weight: 211.352
• Mol File: 16913-62-5.mol
• Article Data: 16

Chemical Properties

• CAS DataBase Reference: Carbamodithioic acid, dimethyl-, 4-methylphenyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Carbamodithioic acid, dimethyl-, 4-methylphenyl ester(16913-62-5)
• EPA Substance Registry System: Carbamodithioic acid, dimethyl-, 4-methylphenyl ester(16913-62-5)

Safety Data

• Hazardous Substances Data: 16913-62-5(Hazardous Substances Data)

Upstream product

• 106-49-0 p-toluidine 
• 16420-13-6 N,N-Dimethylthiocarbamoyl chloride 
• 4294-57-9 para-methylphenylmagnesium bromide 
• 106-45-6 para-thiocresol 
• 108-88-3 toluene 
• 128-04-1 sodium dimethyldithiocarbamate 
• 624-31-7 4-tolyl iodide 
• 137-26-8 Thiram 
• 97-74-5 bis(dimethylthiocarbamoyl)sulfide 
• 5720-05-8 4-methylphenylboronic acid 
• 103-19-5 di(p-tolyl) disulfide 
• 123726-16-9 bis(4-methylphenyl)iodonium trifluoromethanesulfonate 
• 75-15-0 carbon disulfide 
• 124-40-3 dimethyl amine 

Downstream Products

• 65016-87-7 N,N-Dimethyl-(p-tolylmercapto)-formamidchloridbase 
• 788-12-5 1-trifluoromethyl-3-(4-methylphenyl)thiobenzene 
• 92023-43-3 1-chlorophenyl-2-(4-methylphenyl)thiobenzene 
• 620-94-0 di-(p-tolyl)sulfane 
• 59010-83-2 1-methyl-4-(2-hydroxylphenyl)thiobenzene 

Relevant articles and documents

Synthesis of Aryl Dithiocarbamates from Tetramethylthiuram Monosulfide (TMTM) and Aryl Boronic Acids: Copper-Catalyzed Construction of C(sp2)-S Bonds

A highly efficient method for the synthesis of S-aryl dithiocarbamates is reported. By using tetramethylthiuram monosulfide (TMTM) and aryl boronic acids as starting materials, C(sp2)-S bondforming reactions proceed smoothly to give the desired aryl dithiocarbamates in good to excellent yields. The methodology features a simple procedure, broad functional group tolerance and excellent yields, whilst showing potential synthetic value for the preparation of a diverse range of biologically and pharmaceutically active compounds.

Chemoselective C–S/S–S Formation between Diaryl Disulfides and Tetraalkylthiuram Disulfides

An efficient C–S/S–S formation for the chemoselective synthesis of aryl dithiocarbamate (C–S formation) and aryl dialkylcarbamo(dithioperoxo)thioate (S–S formation) was studied. The chemoselectivity could be controlled by modulating the reaction temperature, base, and catalyst. The transformation features a simple reaction, easily available starting materials, high selectivity and easy performance, showing its practical synthetic value for the preparation of some potential biologically or pharmaceutically active compounds.

Synthesis of Phenyl Dithiocarbamates Starting from Sodium Dialkyldithiocarbamates and Aryl Boronic Acids: a Copper Catalyzed S-Arylation

A convenient and efficient protocol for the S-arylation of sodium dialkyldithiocarbamates was developed. With the catalysis of copper(I) bromide, sodium dialkyldithiocarbamates coupled with aryl boronic acids giving the C-S coupling products smoothly in g