169310-77-4

Basic information

• Product Name: Silane, (3-butenyloxy)tris(1-methylethyl)-
• CAS NO: 169310-77-4
• Molecular Formula: C13H28OSi
• Molecular Weight: 228.45
• Mol File: 169310-77-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Silane, (3-butenyloxy)tris(1-methylethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, (3-butenyloxy)tris(1-methylethyl)-(169310-77-4)
• EPA Substance Registry System: Silane, (3-butenyloxy)tris(1-methylethyl)-(169310-77-4)

Safety Data

• Hazardous Substances Data: 169310-77-4(Hazardous Substances Data)

Upstream product

• 627-27-0 homoalylic alcohol 
• 80522-42-5 triisopropylsilyl trifluoromethanesulfonate 

Downstream Products

• 1448775-84-5 1-(2-bromophenyl)-5-(triisopropylsilanyloxy)pentan-1-ol 
• 1448775-83-4 1-(4-chlorophenyl)-5-((triisopropylsilyl)oxy)pentan-1-ol 
• 1448775-70-9 (R)-1-(2-bromophenyl)-5-(triisopropylsilanyloxy)pentan-1-ol 
• 1448775-69-6 (R)-1-(4-chlorophenyl)-5-triisopropylsilanyloxypentan-1-ol 
• 294674-48-9 (R)-4-((R)-3-Isopropyl-6-methyl-cyclohexa-1,5-dienyl)-2-((Z)-1-methyl-4-triisopropylsilanyloxy-but-1-enyl)-5-(3-trimethylsilanyl-prop-2-ynyl)-[1,3]dioxolane 
• 1027170-53-1 4-{2-[3-(4-Benzoyl-phenyl)-propionylamino]-ethoxy}-2-hydroxy-6-(3-methyl-but-2-enyl)-benzoic acid (E)-(S)-4-((E)-4-methoxyimino-but-2-enoylamino)-1-(2-triisopropylsilanyloxy-ethyl)-but-3-enyl ester 
• 1027853-79-7 2-Hydroxy-6-(3-methyl-but-2-enyl)-benzoic acid (E)-(S)-4-{(2E,4E)-6-[3-(4-benzoyl-phenyl)-propionylamino]-hexa-2,4-dienoylamino}-1-(2-triisopropylsilanyloxy-ethyl)-but-3-enyl ester 
• 852327-49-2 2-Allyloxy-4-(2-allyloxycarbonylamino-ethoxy)-6-(3-methyl-but-2-enyl)-benzoic acid (E)-(S)-4-((E)-4-methoxyimino-but-2-enoylamino)-1-(2-triisopropylsilanyloxy-ethyl)-but-3-enyl ester 
• 852327-41-4 2-Allyloxy-6-(3-methyl-but-2-enyl)-benzoic acid (E)-(S)-4-((2E,4E)-6-allyloxycarbonylamino-hexa-2,4-dienoylamino)-1-(2-triisopropylsilanyloxy-ethyl)-but-3-enyl ester 

Relevant articles and documents

Total synthesis of the supposed structure of (-)-sclerophytin A and an improved route to (-)-7-deacetoxyalcyonin acetate.

[reaction: see text]Stereoselective acid-catalyzed rearrangement of 15-->16 is the central step in total syntheses of (-)-7-deacetoxyalcyonin acetate (1) and the compound with the alleged structure of sclerophytin A (2). Since tetracyclic diether 2 is not identical to sclerophytin A, the structure of this antineoplastic marine diterpene must be revised. The conversion of 15-->16 demonstrates for the first time that tetrahydrofurans containing (Z)-1-methylalkenyl side chains can be prepared by Prins-pinacol rearrangements.