170120-19-1Relevant articles and documents
DIOXIRANES IN ORGANOMETALLIC CHEMISTRY. III. DECOMPLEXATION OF TRICARBONYL(η4-DIENE)IRON AND μ-(η2-ALKYNE)HEXACARBONYLDICOBALT COMPLEXES
Lluch, Anna-Maria,Jordi, Lurdes,Sanchez-Baeza, Francisco,Ricart, Susagna,Camps, Francisco,et al.
, p. 407 - 411 (2007/10/02)
The applicability of dimethyldioxirane to the release of organic ligands present in models of the title metal complexes has been studied.In both cases, the decomplexation process takes place at slow rates, with good conversion yields.However, the release of the organic ligand competes with the oxidation of unsaturated moities present in the released compound.This fact should be considered in assessing the advantages of dimethyldioxirane in front of the conventional reagents used for the release of organic ligands from these metal complexes.