17190-71-5Relevant articles and documents
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LaForge,Barthel
, (1947)
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Synthesis of 2,3,5-trisubstituted-2-cyclopentenones via base induced cyclization of alpha-chloro unsaturated ketones
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, (2008/06/13)
2,3,5-trisubstituted-2-cyclopentenones or 2,3-disubstituted-2-cyclopentenones (such as cis-jasmone) are prepared by contacting a 3-chloro-3,4-disubstituted-4-pentene-2-one with a strong base. Methods of preparing the reactants are also disclosed.
Process for producing cis-jasmone
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, (2008/06/13)
A process is described for the preparation of cis-jasmone according to the reaction: STR1 wherein X is chloro or bromo and wherein M is alkali metal, the reaction being carried out (1) using a phase transfer agent and (2) in a two phase system.