172371-55-0

Basic information

• Product Name: 10,15-Dihydro-2,7,12-trimethoxy-3,8,13-tris(4-allyloxybenzyloxy)-5H-tribenzocyclononene
• CAS NO: 172371-55-0
• Molecular Weight: 847.017
• Mol File: 172371-55-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 10,15-Dihydro-2,7,12-trimethoxy-3,8,13-tris(4-allyloxybenzyloxy)-5H-tribenzocyclononene(CAS DataBase Reference)
• NIST Chemistry Reference: 10,15-Dihydro-2,7,12-trimethoxy-3,8,13-tris(4-allyloxybenzyloxy)-5H-tribenzocyclononene(172371-55-0)
• EPA Substance Registry System: 10,15-Dihydro-2,7,12-trimethoxy-3,8,13-tris(4-allyloxybenzyloxy)-5H-tribenzocyclononene(172371-55-0)

Safety Data

• Hazardous Substances Data: 172371-55-0(Hazardous Substances Data)

Upstream product

• 3256-45-9 4-allyloxybenzyl alcohol 
• 32078-38-9 4-allyloxybenzyl chloride 
• 81370-49-2 cyclotriguaiacyclene 

Relevant articles and documents

Rhodium(I)-centered cyclotriveratrylene

The rigid bowl-shaped molecule cyclotriveratrylene (CTV,1) was provided with short and long spacer arms terminating in triphenyl phosphite functions.These CTV ligands were used to immobilize a rhodium(I)-carbonyl-hydride complex.The ligand with short spacers gave a rigid, strained complex with a trigonal-coordination sphere around the rhodium.The ligand with long flexible spacers allowed the formation of a large cavity after the complexation to the rhodium center.This cavity, however, is filled up by the spacer arms, as was indicated by NMR studies.Variable-temperature NMR experiments suggested that the H-Rh-CO dipole in the rhodium-CTV complex can adopt two orientations: one with the hydride group pointing away from the CTV cavity (low-temperature conformation) and one in which this orientation is inverted (high-temperature conformation).