17381-60-1Relevant articles and documents
Generation of iodobenzoborirene, a boraaromatic cyclopropabenzene derivative
Bettinger, Holger F.
, p. 2756 - 2757 (2007/10/03)
Iodobenzoborirene is obtained photochemically (λ = 308 nm) from diiodophenylborane by elimination of HI in solid argon at 10 K. The Royal Society of Chemistry 2005.
Reaction of the small closo carboranes 1,6-C2B4H6 and 2,4-C2B5H7 with BX3 (X = halogen, phenyl): A method of preparing 3 -Substituted 2,4-C2B5H7 derivatives and preparation of 2-Br2B-closo-1,6-C2B4H5
Nam, Wonwoo,Onak, Thomas
, p. 48 - 52 (2008/10/08)
The reaction of closo-2,4-C2B5H7 with BX3 (X = Cl, Br, I, C6H5) at elevated temperatures (270°C for BCl3, 160°C for BBr3, 120°C for BI3, 160°C for B(C6H5)3) results in halogen, or phenyl, substitution primarily at the 3-position of the carborane (i.e. 3-X-closo-2,4-C2B5H6). closo-2,4-C2B5H7 also reacts with (CH3)3CCl at 270°C to give 3-Cl-closo-2,4-C2B5H6. A closo carborane containing a trigonal boron σ-bonded to a cage carborane, 2-Br2B-closo-1,6-C2B4H5, is prepared from closo-1,6-C2B4H6 and BBr3 at 265°C.
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Siebert, Walter,Rittig, Falk R.,Schmidt, Max
, p. 511 - 524 (2007/10/05)
The redox reaction between iodoboranes and disulfanes leads to thioboranes of the composition RSBX2, (RS)2BX and (RS)3B in very good yields. The compounds of the type RSBX2 show different thermal and hydrolytica
