1739-10-2

Basic information

• Product Name: N-(4-phenylbutyl)benzenamine
• Synonyms: N-(4-phenylbutyl)benzenamine
• CAS NO: 1739-10-2
• Molecular Weight: 225.334
• Mol File: 1739-10-2.mol
• Article Data: 15

Chemical Properties

• CAS DataBase Reference: N-(4-phenylbutyl)benzenamine(CAS DataBase Reference)
• NIST Chemistry Reference: N-(4-phenylbutyl)benzenamine(1739-10-2)
• EPA Substance Registry System: N-(4-phenylbutyl)benzenamine(1739-10-2)

Safety Data

• Hazardous Substances Data: 1739-10-2(Hazardous Substances Data)

Upstream product

• 300-57-2 allylbenzene 
• 17890-12-9 N-Phenyl-N-<(trimethylsilyl)methyl>amine 
• 62-53-3 aniline 
• 29369-71-9 N-(3-butenyl)aniline 
• 98-80-6 phenylboronic acid 
• 3360-41-6 4-phenyl-butan-1-ol 
• 13214-66-9 4-phenyl-1-butylamine 
• 108-95-2 phenol 
• 1821-12-1 4-Phenylbutyric acid 
• 768-56-9 4-Phenylbut-1-ene 
• 100-61-8 N-methylaniline 
• 3240-29-7 1-Phenylpent-4-en-1-one 
• 56139-59-4 4-oxo-4-phenyl-butyraldehyde 
• 98-95-3 nitrobenzene 

Relevant articles and documents

Ureate Titanium Catalysts for Hydroaminoalkylation: Using Ligand Design to Increase Reactivity and Utility

Hydroaminoalkylation describes the atom-economical catalytic synthesis of amines by forming new Csp3-Csp3 bonds using readily available amine and alkene feedstocks. Herein, we describe an earth-abundant and cost-efficient titanium catalyst generated in si

Linear Hydroaminoalkylation Products from Alkyl-Substituted Alkenes

The regioselective conversion of alkyl-substituted alkenes into linear hydroaminoalkylation products represents a strongly desirable synthetic transformation. In particular, such conversions of N-methylamine derivatives are of great scientific interest, because they would give direct access to important amines with unbranched alkyl chains. Herein, we present a new one-pot procedure that includes an initial alkene hydroaminoalkylation with an α-silylated amine substrate and a subsequent protodesilylation reaction that delivers linear hydroaminoalkylation products with high selectivity from simple alkyl-substituted alkenes. For that purpose, new titanium catalysts have been developed, which are able to activate the α-C?H bond of more challenging α-silylated amine substrates. In addition, a direct relationship between the ligand structure of the new catalysts and the obtained regioselectivity is described.

Dehydroxylation of alcohols for nucleophilic substitution

The Ph3P/ICH2CH2I system-promoted dehydroxylative substitution of alcohols was achieved to construct C-O, C-N, C-S and C-X (X = Cl, Br, and I) bonds. Compared with the previous approaches such as the Appel reaction and Mitsunobu reaction, this protocol offers some practical advantages such as safe operation and a convenient amination process.