174222-80-1

Basic information

• Product Name: ((CH₃)5C₅)Ir(Cl)(OC(O)CH(C₆H₅)N(CH₃)2)
• Synonyms: ((CH₃)5C₅)Ir(Cl)(OC(O)CH(C₆H₅)N(CH₃)2)
• CAS NO: 174222-80-1
• Molecular Weight: 541.113
• Mol File: 174222-80-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: ((CH₃)5C₅)Ir(Cl)(OC(O)CH(C₆H₅)N(CH₃)2)(CAS DataBase Reference)
• NIST Chemistry Reference: ((CH₃)5C₅)Ir(Cl)(OC(O)CH(C₆H₅)N(CH₃)2)(174222-80-1)
• EPA Substance Registry System: ((CH₃)5C₅)Ir(Cl)(OC(O)CH(C₆H₅)N(CH₃)2)(174222-80-1)

Safety Data

• Hazardous Substances Data: 174222-80-1(Hazardous Substances Data)

Upstream product

• 19701-89-4 N,N-dimethylalanine 

Relevant articles and documents

Highly stereoselective formation of Cp*IrCl complexes of N,N-dimethylamino acids

N,N-Dimethylamino acids serve as (N, O)-chelating monoanionic ligands to the prochiral fragment Cp*IrCl. A series of four such complexes and one Rh analog all were formed with diastereoselectivity of >50:17H29ClIrNO2) was analyzed at 298 K, from which a cis-arrangement of Cp* and valine side chain (i-Pr) was revealed. Solution NMR studies of 5d, aided by an unusual zero coupling between the two methine protons of the amino acid, showed that the structures in solution and the solid were very similar. The preference for the cis-oriented Cp* and amino acid side chain in 5 is attributed to a maximum number of gauche interactions in the metallacycle and its substituents, especially pronounced for N,N-disubstituted amino acids.