17540-19-1

Basic information

• Product Name: (3R)-3α-Phenyl-1-cyclohexene
• Synonyms: (3R)-3α-Phenyl-1-cyclohexene;(R)-3-Phenylcyclohexene;[(1R)-2-Cyclohexene-1β-yl]benzene;[R,(+)]-3-Phenylcyclohexene
• CAS NO: 17540-19-1
• Molecular Formula: C12H14
• Molecular Weight: 158.23956
• Mol File: 17540-19-1.mol
• Article Data: 24

Chemical Properties

• Appearance: /
• CAS DataBase Reference: (3R)-3α-Phenyl-1-cyclohexene(CAS DataBase Reference)
• NIST Chemistry Reference: (3R)-3α-Phenyl-1-cyclohexene(17540-19-1)
• EPA Substance Registry System: (3R)-3α-Phenyl-1-cyclohexene(17540-19-1)

Safety Data

• Hazardous Substances Data: 17540-19-1(Hazardous Substances Data)

Upstream product

• 2362-61-0 trans-2-Phenylcyclohexanol 
• 22040-54-6 trans-(+/-)-1-Acetoxy-2-phenylcyclohexane 
• 22040-54-6 cis-2-phenyl-cyclohexyl acetate 
• 17540-17-9 (+/-)-dithiocarbonic acid S-methyl ester-O-(trans-2-phenyl-cyclohexyl ester) 
• 17540-17-9 (+/-)-dithiocarbonic acid S-methyl ester-O-(cis-2-phenyl-cyclohexyl ester) 
• 97395-16-9 optically inactive sulfurous acid methyl ester-(trans-2-phenyl-cyclohexyl ester) 
• 97395-16-9 optically inactive sulfurous acid methyl ester-(cis-2-phenyl-cyclohexyl ester) 
• 1521-51-3 rac-3-bromocyclohexene 
• 107-10-8 propylamine 
• 771-98-2 1-Phenylcyclohexene 
• 26974-24-3 6-phenyl-1-pyrrolidinocyclohexene 
• 1444-64-0 2-phenylcyclohexanol 
• 2362-61-0 cis-2-phenylcyclohexanol 
• 127-09-3 sodium acetate 

Downstream Products

• 771-98-2 1-Phenylcyclohexene 

Relevant articles and documents

Efficient functionalization of olefins by arylsilanes catalyzed by palladium anionic complexes

The coupling of organosilanes and different olefins was performed efficiently in the presence of anionic complexes, [CA]2[PdX4] and [CA]2[Pd2X6], where CA?=?imidazolium or pyridinium cation. The reaction proceeds according to a Pd(II)-mediated pathway, and Cu(OAc)2 acts as the re-oxidant of Pd(0) formed during the catalytic process. High product yields were obtained for differently substituted olefins at 80?°C in 4?h. Styrylsilanes reacted in the same conditions giving unsymmetrical 1,3-dienes.

Bidentate hydroxyalkyl NHC ligands for the copper-catalyzed asymmetric allylic substitution of allyl phosphates with grignard reagents

Demonstrating their potential: Bidentate alkoxy NHC ligands have been used in the copper-catalyzed asymmetric allylic alkylation of allyl phosphates with Grignard reagents (see scheme). The method provides access to tertiary and quaternary chiral centers with high regio- and enantioselectivity. The system is also applied to the synthesis of chiral E,E-dienes, a key structural motif prevalent in natural products. Copyright

Selective heck arylation of cyclohexene with homogeneous and heterogeneous palladium catalysts

Palladium catalysts containing Pd(II) supported on Al2O 3 and alumina-based mixed oxides, Al2O3- ZrO2, Al2O3-CeO2, and Al 2O3-Fe2O3, are very effective in the Heck coupling of iodobenzene with cyclohexene in DMF solution. The best results, up to 81% of monoarylated products with a selectivity to 4-phenylcyclohexene (3) close to 90% were obtained with KOH as a base. The catalytic activity of palladium supported on aluminabased oxides was compared with that of homogeneous precursors, such as Pd(OAc)2 and PdCl 2(PhCN)2, used in [Bu4N]Br as the reaction medium. Under such conditions homogeneous systems were more selective and produced up to 60% of monoarylated products with a selectivity to 3 close to 60%. Copyright