176981-55-8

Basic information

• Product Name: Pt(C₁₀H₇N₂(C₆H₄))(P(C₆H₅)3)⁽¹⁺⁾*ClO₄^(1-)=[Pt(C₁₀H₇N₂(C₆H₄))(P(C₆H₅)3)]ClO₄
• CAS NO: 176981-55-8
• Molecular Weight: 788.098
• Mol File: 176981-55-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Pt(C₁₀H₇N₂(C₆H₄))(P(C₆H₅)3)⁽¹⁺⁾*ClO₄^(1-)=[Pt(C₁₀H₇N₂(C₆H₄))(P(C₆H₅)3)]ClO₄(CAS DataBase Reference)
• NIST Chemistry Reference: Pt(C₁₀H₇N₂(C₆H₄))(P(C₆H₅)3)⁽¹⁺⁾*ClO₄^(1-)=[Pt(C₁₀H₇N₂(C₆H₄))(P(C₆H₅)3)]ClO₄(176981-55-8)
• EPA Substance Registry System: Pt(C₁₀H₇N₂(C₆H₄))(P(C₆H₅)3)⁽¹⁺⁾*ClO₄^(1-)=[Pt(C₁₀H₇N₂(C₆H₄))(P(C₆H₅)3)]ClO₄(176981-55-8)

Safety Data

• Hazardous Substances Data: 176981-55-8(Hazardous Substances Data)

Upstream product

• 61633-06-5 6-phenyl-2,2'-bipyridine 
• 603-35-0 triphenylphosphine 

Relevant articles and documents

Photoluminescent cyclometallated diplatinum(II,II) complexes: photophysical properties and crystal structures of ClO4 and 2 (HL=6-phenyl-2,2'-bipyridine, dppm=Ph2PCH2PPh2)

The complexes 1, ClO4 2 and 2 3 (HL=6-phenyl-2,2'-bipyridine, dppm=Ph2PCH2PPh2) have been prepared and their spectroscopic and emission properties studied.Complex 3 shows a broad and intense absorption at 420-510 nm which is tentatively assigned to a metal-metal to ligand charge-transfer transition 1m.m.l.c.t. 1?*->?(?*)>, where d?* arises from the antisymmetric combination of the two platinum dz2 orbitals and ?(?*) from the symmetric combination of ?* orbitals of the two L ligands.All the complexes show luminescence in both the solid state and in solution.Both 1 and 2 display 3m.l.c.t. emission in solution at room temperature.The solid state emission of 1 and both the solid-state and fluid-state emission of 3 are assigned to the 3m.m.l.c.t. 3?*)*)> state.The crystal structure of 2 shows an intermolecular ?-? interaction between two L ligands as evidenced by the intermolecular ligand plane separation of 3.35 Angstroem.The solid-state emission of 2 is suggested to arise from a ?-? excimeric interaction of the L ligands.The crystal structure of 3 shows discrete 2+ units with an intramolecular Pt-Pt separation of 3.2703 Angstroem.