177093-14-0

Basic information

• Product Name: trans-1-Phenyl-4-tert-butylbut-2-ene-1,4-dione
• Synonyms: trans-1-Phenyl-4-tert-butylbut-2-ene-1,4-dione
• CAS NO: 177093-14-0
• Molecular Weight: 216.28
• Mol File: 177093-14-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: trans-1-Phenyl-4-tert-butylbut-2-ene-1,4-dione(CAS DataBase Reference)
• NIST Chemistry Reference: trans-1-Phenyl-4-tert-butylbut-2-ene-1,4-dione(177093-14-0)
• EPA Substance Registry System: trans-1-Phenyl-4-tert-butylbut-2-ene-1,4-dione(177093-14-0)

Safety Data

• Hazardous Substances Data: 177093-14-0(Hazardous Substances Data)

Upstream product

• 94743-26-7 2,2-dimethyl-6-phenylhexan-3-one 
• 1074-12-0 phenylglyoxal hydrate 

Downstream Products

• 186707-59-5 1-((2R,3R)-3-Benzoyl-oxiranyl)-2,2-dimethyl-propan-1-one 

Relevant articles and documents

Aerobic Oxidative Dehydrogenation of Ketones to 1,4-Enediones

An efficient and unprecedented strategy for the synthesis of 1,4-enediones from saturated ketones has been developed via palladium-catalyzed oxidative dehydrogenation. The protocol employs molecular oxygen as the sole oxidant and represents an atom- and step-economic process. The approach showed broad substrate scope, good functional group tolerance, and complete E-stereoselectivity. The reaction mechanism has been investigated through deuterium-labeling experiments and intermediate experiments.