1779-57-3

Basic information

• Product Name: (Triphenylphosphonio)-(methoxycarbonyl)dideuteriomethanbromide
• Synonyms: (Triphenylphosphonio)-(methoxycarbonyl)dideuteriomethanbromide
• CAS NO: 1779-57-3
• Molecular Weight: 417.25
• Mol File: 1779-57-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (Triphenylphosphonio)-(methoxycarbonyl)dideuteriomethanbromide(CAS DataBase Reference)
• NIST Chemistry Reference: (Triphenylphosphonio)-(methoxycarbonyl)dideuteriomethanbromide(1779-57-3)
• EPA Substance Registry System: (Triphenylphosphonio)-(methoxycarbonyl)dideuteriomethanbromide(1779-57-3)

Safety Data

• Hazardous Substances Data: 1779-57-3(Hazardous Substances Data)

Upstream product

• 163886-16-6 methyl bromoacetate-2,2-²H₂ 
• 603-35-0 triphenylphosphine 

Relevant articles and documents

An unexpected role of a trace amount of water in catalyzing proton transfer in phosphine-catalyzed (3 + 2) cycloaddition of allenoates and alkenes

Through the joint forces of computation and experiment, the detailed mechanism of the Lu phosphine catalyzed (3 + 2) cycloaddition of allenoates and alkenes has been elucidated. The overall potential energy surface of the Lu (3 + 2) reaction has been computed. More importantly, theory and experiment have confirmed that a trace amount of water plays a critical role in assisting the process of [1,2] proton shift in the Lu reaction. Copyright