17802-36-7

Basic information

• Product Name: 3,4-Dimethyldiphenylamine
• Synonyms: 3,4-Dimethyldiphenylamine;3,4-dimethyl-n-phenyl-benzenamine;Benzenamine,3,4-dimethyl-N-phenyl-;3,4imethyltriphenylamine;3,4-Dimethyltriphenylamine 3,4-Dimethyl-N-phenyl-benzenamine;3,4-diMethyl-N-phenylaniline;N-Phenyl-3,4-xylidine Phenyl(3,4-xylyl)amine;N-Phenyl-3,4-Xylidine
• CAS NO: 17802-36-7
• Molecular Formula: C₁₄H₁₅N
• Molecular Weight: 197.28
• EINECS: 1533716-785-6
• Product Categories: electronic
• Mol File: 17802-36-7.mol
• Article Data: 9

Chemical Properties

• Melting Point: 57°C
• Boiling Point: 333.3 °C at 760 mmHg
• Flash Point: 163.6 °C
• Appearance: White crystal
• Density: 1.049 g/cm³
• Vapor Pressure: 0.000138mmHg at 25°C
• Refractive Index: 1.611
• Storage Temp.: Keep in dark place,Inert atmosphere,Room temperature
• PKA: 1.42±0.50(Predicted)
• CAS DataBase Reference: 3,4-Dimethyldiphenylamine(CAS DataBase Reference)
• NIST Chemistry Reference: 3,4-Dimethyldiphenylamine(17802-36-7)
• EPA Substance Registry System: 3,4-Dimethyldiphenylamine(17802-36-7)

Safety Data

• Hazardous Substances Data: 17802-36-7(Hazardous Substances Data)

Usage

Chemical Properties

White crystalline

InChI:InChI=1/C14H15N/c1-11-8-9-14(10-12(11)2)15-13-6-4-3-5-7-13/h3-10,15H,1-2H3

Upstream product

• 95-47-6 o-xylene 
• 622-37-7 Phenyl azide 
• 603-33-8 triphenylbismuthane 
• 95-64-7 4-amino-o-xylene 
• 325723-04-4 Phenylbiphenyl-2,2'-ylenebismuth diacetate 
• 31599-61-8 3,4-dimethyliodobenzene 
• 62-53-3 aniline 
• 5465-09-8 3,4-dimethylcyclohexanone 
• 108-91-8 cyclohexylamine 
• 108-94-1 cyclohexanone 
• 583-71-1 4-bromo-o-xylene 
• 108-86-1 bromobenzene 
• 39492-53-0 2-[N-(2,3-dimethylphenyl)amino]benzoic acid 
• 98-80-6 phenylboronic acid 

Relevant articles and documents

Copper immobilized at a covalent organic framework: An efficient and recyclable heterogeneous catalyst for the Chan-Lam coupling reaction of aryl boronic acids and amines

A polyimide covalent organic framework (PI-COF) with high thermal and chemical stabilities has been readily prepared from commercially available and inexpensive reagents and was employed as an effective support for heterogeneous copper. It was demonstrated that the obtained Cu@PI-COF is a highly active heterogeneous catalyst which can effectively promote the Chan-Lam coupling reaction of aryl boronic acids and amines in an open flask without the aid of any base or additive. In addition, the catalyst could be readily recovered from the reaction mixture by simple filtration and reused for at least eight cycles without any observable change in structure and catalytic activity.

Ruthenium and palladium complexes incorporating amino-azo-phenol ligands: Synthesis, characterization, structure and reactivity

The ligands 2-((2-aminophenyl)diazenyl)phenol, HOL1-NH2, 1a; 2-((2-aminophenyl)diazenyl)-5-methylphenol, HOL2-NH2, 1b; and 2-((2-aminophenyl) diazenyl)-5-chlorophenol, HOL3-NH2, 1c, which are abbreviated as HOL-NH2, 1, afforded the complexes of compositions [(OL-NH)Pd(PPh3)], 2, and [(OL-NH)Ru(CO)(PPh3)2], 3, upon reaction with Na2PdCl4 and Ru(CO)3(PPh3)3 respectively. In all the complexes the metals ions, Pd(II) or Ru(II), are coordinated by deprotonated ligand (OL-NH)2- in tridentate (N, N, O) fashion. X-ray structures of [(OL2-NH)Pd(PPh3)], 2b, and [(OL1-NH)Ru(CO)(PPh3)2], 3a, were determined to confirm the molecular structures. The cyclic voltammograms of [(OL-NH)Ru(CO)(PPh3)2] exhibited two quasi reversible oxidative response near 0.25 and 1.12 V vs. SCE. The nature of HOMO as obtained by DFT calculations has been inspected to have an insight into the redox orbitals. The newly synthesized [(OL-NH)Pd(PPh3)], 2a, complexes exhibited catalytic activity toward the Suzuki, Heck, Cyanation and amination reactions. Catalytic activity of complex [(OL1-NH)Ru(CO)(PPh3)2], 3a, was examined for the conversion of ketones to corresponding alcohols by transfer hydrogen reactions.

RAPID, COST EFFECTIVE METHOD FOR SYNTHESIS OF DIARYLAMINE COMPOUNDS

A process for forming a diarylamine compound, including reacting an aniline and an arylbromide in the presence of a palladium ligated catalyst and a base.