17913-10-9

Basic information

• Product Name: 4-phenylpentan-2-one
• Synonyms: 4-phenylpentan-2-one;4-Phenyl-2-pentanone;Einecs 241-857-2
• CAS NO: 17913-10-9
• Molecular Formula: C₁₁H₁₄O
• Molecular Weight: 162.22826
• EINECS: 241-857-2
• Mol File: 17913-10-9.mol
• Article Data: 68

Chemical Properties

• Boiling Point: 230.2°Cat760mmHg
• Flash Point: 90.3°C
• Appearance: /
• Density: 0.956g/cm³
• Vapor Pressure: 0.0666mmHg at 25°C
• Refractive Index: 1.498
• CAS DataBase Reference: 4-phenylpentan-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: 4-phenylpentan-2-one(17913-10-9)
• EPA Substance Registry System: 4-phenylpentan-2-one(17913-10-9)

Safety Data

• Hazardous Substances Data: 17913-10-9(Hazardous Substances Data)

Usage

Synthesis Reference(s)

Tetrahedron Letters, 25, p. 5467, 1984 DOI: 10.1016/S0040-4039(01)81600-2

InChI:InChI=1/C11H14O/c1-9(8-10(2)12)11-6-4-3-5-7-11/h3-7,9H,8H2,1-2H3

Upstream product

• 1569-50-2 3-penten-2-ol 
• 62-38-4 phenylmercuric acetate 
• 31731-86-9 2-phenylpropylmagnesium bromide 
• 75-07-0 acetaldehyde 
• 15681-48-8 lithium dimethylcuprate 
• 1896-62-4 (E)-benzalacetone 
• 51384-73-7 4-phenyl-3-penten-2-one 
• 595-90-4 tetraphenyltin(IV) 
• 3102-33-8 trans-3-penten-2-one 
• 625-33-2 3-penten-2-one 
• 909413-25-8 6-(tert-butyl)-12-phenyl-5,6,7,12-tetrahydrodibenzo[c,f][1,5]azastibocine 
• 945-93-7 ethyl (E)-3-phenylbut-2-enoate 
• 141868-93-1 (E)-N-methoxy-N-methyl-3-phenylbut-2-enamide 
• 108-22-5 Isopropenyl acetate 

Downstream Products

• 33484-99-0 2-Chloro-2-methyl-4-phenylpentane 
• 4593-90-2 3-phenylbutyric acid 
• 65170-88-9 4-(p-Iso-butyrylphenyl)-2-pentanone 
• 65170-91-4 4-(4-benzoylphenyl)pentan-2-one 
• 77614-49-4 4-phenyl-pentan-2-ol 
• 1381772-32-2 (Z)-1-(4-phenylpentan-2-ylidene)-2-p-tolylhydrazine 
• 1381772-28-6 (E)-1-(4-phenylpentan-2-ylidene)-2-p-tolylhydrazine 
• 1381772-31-1 (Z)-1-(4-chlorophenyl)-2-(4-phenylpentan-2-ylidene)hydrazine 
• 1381772-27-5 (E)-1-(4-chlorophenyl)-2-(4-phenylpentan-2-ylidene)hydrazine 
• 1381772-65-1 (E)-1-(2-chloro-4-phenylpentan-2-yl)-2-p-tolyldiazene 
• 1381772-63-9 (E)-1-(2-chloro-4-phenylpentan-2-yl)-2-(4-chlorophenyl)diazene 
• 32587-80-7 (S)-4-phenylpentan-2-one 
• 67110-72-9 (4R)-4-phenylpentan-2-one 
• 50373-50-7 acetic acid (S)-(-)-2-phenyl-1-propanol ester 

Relevant articles and documents

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On the Way to Chiral Copper(I) Arenethiolate Catalysts for the Enantioselective Conjugate Addition of Methyl Lithium and Methyl Magnesium Iodide to Benzylideneacetone

Selective conjugate addition (0 percent enantiomeric excess (e.e)) of organoarenethiolatocuprates (from methyl lithium and 2-phenylthiolatocopper(I), CuSAr*) to benzylideneacetone (BA) is found up to a LiMe/CuSAr* ratio of 2/1

Asymmetric Umpolung Hydrogenation and Deuteration of Alkenes Catalyzed by Nickel

Nickel-catalyzed asymmetric hydrogenation of several types of alkenes proceeds in high enantioselectivity, using acetic acid or water as the hydrogen source and indium powder as electron donor. The scope of alkenes herein include α,β-unsaturated esters, n

In Situ Generated Gold Nanoparticles on Active Carbon as Reusable Highly Efficient Catalysts for a Csp3 ?Csp3 Stille Coupling

Gold nanoparticle catalysts are important in many industrial production processes. Nevertheless, for traditional Csp2-Csp2 cross-coupling reactions they have been rarely used and Pd catalysts usually give a superior performance. Herein we report that in situ formed gold metal nanoparticles are highly active catalysts for the cross coupling of allylstannanes and activated alkylbromides to form Csp3-Csp3 bonds. Turnover numbers up to 29 000 could be achieved in the presence of active carbon as solid support, which allowed for convenient catalyst recovery and reuse. The present study is a rare case where a gold metal catalyst is superior to Pd catalysts in a cross-coupling reaction of an organic halide and an organometallic reagent.