17979-81-6

Basic information

• Product Name: SODIUM TRIETHYLBOROHYDRIDE
• Synonyms: SODIUM TRIETHYLBOROHYDRIDE;sodium triethylhydroborate(1-);SODIUM TRIETHYLBOROHYDRIDE, 1.0M SOLUTIO N IN TETRAHYDROFURAN;SODIUM TRIETHYLBOROHYDRIDE SOLUTION, ~1 M IN THF;SODIUM TRIETHYLBOROHYDRIDE, 1.0M SOLUTIO N IN TOLUENE;Sodium triethylborohydride, 1 M solution in tetrahydrofuran;Borate(1-), triethylhydro-, sodium, (T-4)-;sodium triethylborohydride solution
• CAS NO: 17979-81-6
• Molecular Formula: C6H16BNa
• Molecular Weight: 121.99
• EINECS: 241-903-1
• Product Categories: Borohydrides;Reduction;Synthetic Reagents
• Mol File: 17979-81-6.mol
• Article Data: 0

Chemical Properties

• Flash Point: 45 °F
• Appearance: Colorless/Solution
• Density: 0.89 g/mL at 25 °C
• Storage Temp.: Flammables + water-Freezer (-20°C)e area
• BRN: 4151241
• CAS DataBase Reference: SODIUM TRIETHYLBOROHYDRIDE(CAS DataBase Reference)
• NIST Chemistry Reference: SODIUM TRIETHYLBOROHYDRIDE(17979-81-6)
• EPA Substance Registry System: SODIUM TRIETHYLBOROHYDRIDE(17979-81-6)

Safety Data

• Hazard Codes: F,Xn,C
• Statements: 11-14/15-34-48/20-63-65-67-37-19-40
• Safety Statements: 26-36/37/39-43-45-62-16
• RIDADR: UN 3399 4.3/PG 1
• WGK Germany: 2
• F: 10
• Hazardous Substances Data: 17979-81-6(Hazardous Substances Data)

Usage

Description

SODIUM TRIETHYLBOROHYDRIDE is a colorless solution that serves as a versatile reagent in various chemical reactions due to its unique properties. It is known for its ability to act as a hydridic reagent, participating in coordinative substitution reactions, ligand exchange reactions, and the preparation of alkali metal boron monohydride complexes.

Uses

Used in Chemical Synthesis:
SODIUM TRIETHYLBOROHYDRIDE is used as a reactant for the preparation of alcohols by hydrogenation of ketones, catalyzed by an iron pincer complex. This application is particularly useful in the synthesis of various organic compounds, as it allows for the selective reduction of ketones to alcohols under mild conditions.
Used in Coordination Chemistry:
In the field of coordination chemistry, SODIUM TRIETHYLBOROHYDRIDE is used as a reactant for the preparation of alkali metal boron monohydride complexes. These complexes are important intermediates in the synthesis of various organoboron compounds and have potential applications in materials science and pharmaceuticals.
Used in Ligand Exchange and Substitution Reactions:
SODIUM TRIETHYLBOROHYDRIDE is also used as a reactant in ligand exchange and coordinative substitution reactions. Its ability to act as a hydridic reagent makes it a valuable tool for modifying the coordination environment of metal centers, which can be crucial in the development of new catalysts and materials with tailored properties.
Overall, SODIUM TRIETHYLBOROHYDRIDE is a valuable reagent in the fields of chemical synthesis, coordination chemistry, and materials science, due to its unique properties and versatility in various types of reactions.