181523-24-0

Basic information

• Product Name: Benzene, 1-iodo-4-tetradecyl-
• CAS NO: 181523-24-0
• Molecular Formula: C20H33I
• Molecular Weight: 400.387
• Mol File: 181523-24-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzene, 1-iodo-4-tetradecyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-iodo-4-tetradecyl-(181523-24-0)
• EPA Substance Registry System: Benzene, 1-iodo-4-tetradecyl-(181523-24-0)

Safety Data

• Hazardous Substances Data: 181523-24-0(Hazardous Substances Data)

Upstream product

• 91323-12-5 4-tetradecylaniline 
• 536985-44-1 1-(diacetoxyiodo)-4-tetradecylbenzene 
• 479-33-4 2,3,4,5-tetraphenylcyclopenta-2,4-dienone 
• 1027537-24-1 (4-tetradecylphenyl)[2-(trimethylsilyl)phenyl]iodonium triflate 
• 110-00-9 furan 

Downstream Products

• 1027537-24-1 (4-tetradecylphenyl)[2-(trimethylsilyl)phenyl]iodonium triflate 
• 536985-44-1 1-(diacetoxyiodo)-4-tetradecylbenzene 

Relevant articles and documents

Improved solubility of hypervalent iodine-benzyne precursors: Synthesis and reaction of (phenyl)[2-(trimethylsilyl)phenyl]iodonium salts bearing long alkyl chains

Synthesis of new long-chained hypervalent iodine-benzyne precursors, (4-dodecylphenyl)[2-(trimethylsilyl)phenyl]iodonium triflate and the tetradecyl derivative, is described. The benzyne precursors dissolve even in organic solvents of low polarity such as diethyl ether, THF, cyclopentyl methyl ether, benzene, and toluene. The trapping reactions with furan and tetraphenylcy-clopentadienone in the above solvent give the benzyne adducts in high yields without any loss of high reactivity of hypervalent iodine-benzyne precursors.