1820817-64-8

Basic information

• Product Name: Methanesulfonato{[4-(N,N-dimethylamino)phenyl]di-t-butylphosphino}(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98% [Amphos Palladacycle Gen. 3]
• Synonyms: Methanesulfonato{[4-(N,N-dimethylamino)phenyl]di-t-butylphosphino}(2'-amino-1,1'-biphenyl-2-yl)palladium(II),[Amphos Palladacycle Gen. 3]
• CAS NO: 1820817-64-8
• Molecular Formula: C29H41N2O3PPdS
• Molecular Weight: 635.11
• Product Categories: GLKM-3855
• Mol File: 1820817-64-8.mol
• Article Data: 1

Chemical Properties

• Appearance: beige to tan/Powder
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• CAS DataBase Reference: Methanesulfonato{[4-(N,N-dimethylamino)phenyl]di-t-butylphosphino}(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98% [Amphos Palladacycle Gen. 3](CAS DataBase Reference)
• NIST Chemistry Reference: Methanesulfonato{[4-(N,N-dimethylamino)phenyl]di-t-butylphosphino}(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98% [Amphos Palladacycle Gen. 3](1820817-64-8)
• EPA Substance Registry System: Methanesulfonato{[4-(N,N-dimethylamino)phenyl]di-t-butylphosphino}(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98% [Amphos Palladacycle Gen. 3](1820817-64-8)

Safety Data

• Hazardous Substances Data: 1820817-64-8(Hazardous Substances Data)

Usage

Uses

APhos Pd G3 is a Buchwald precatalyst that can be used in cross-coupling reactions.

Upstream product

• 932710-63-9 (4-(N,N-dimethylamino)phenyl)-di-tert-butylphosphine 

Relevant articles and documents

Late-Stage Functionalization of the Periphery of Oligophenylene Dendrimers with Various Arene Units via Fourfold C-H Borylation

Late-stage functionalization of the periphery of oligophenylene dendrimers was efficiently achieved via site-selective C-H activation of a preconstructed, readily accessible dendron. By fourfold iridium-catalyzed C-H borylation followed by Suzuki-Miyaura cross-coupling, various arene units were introduced into the end points of the 1,3,5-phenylene-based hydrocarbon dendron. Coupling of the modified dendrons with a core unit, such as 2,6-dibromobenzoic acid derivatives, afforded the periphery-functionalized dendrimers that also have an endohedral functionality at the core position.