182167-68-6

Basic information

• Product Name: Benzoic acid (2R,3R,5R,6R)-6-ethylsulfanyl-5-(4-methoxy-benzyloxy)-2-methyl-tetrahydro-pyran-3-yl ester
• CAS NO: 182167-68-6
• Molecular Weight: 416.538
• Mol File: 182167-68-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzoic acid (2R,3R,5R,6R)-6-ethylsulfanyl-5-(4-methoxy-benzyloxy)-2-methyl-tetrahydro-pyran-3-yl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid (2R,3R,5R,6R)-6-ethylsulfanyl-5-(4-methoxy-benzyloxy)-2-methyl-tetrahydro-pyran-3-yl ester(182167-68-6)
• EPA Substance Registry System: Benzoic acid (2R,3R,5R,6R)-6-ethylsulfanyl-5-(4-methoxy-benzyloxy)-2-methyl-tetrahydro-pyran-3-yl ester(182167-68-6)

Safety Data

• Hazardous Substances Data: 182167-68-6(Hazardous Substances Data)

Upstream product

• 182167-61-9 Toluene-4-sulfonic acid (3aS,4R,6R,7R,7aS)-6-methoxy-7-(4-methoxy-benzyloxy)-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-4-ylmethyl ester 
• 182167-63-1 Methyl 3,4-O-isopropylidene-2-O-(p-methoxybenzyl)-β-D-fucopyranoside 
• 182167-64-2 Methyl 2-O-(p-methoxybenzyl)-β-D-fucopyranoside 
• 182167-66-4 (2R,3R,5R,6R)-6-Methoxy-5-(4-methoxy-benzyloxy)-2-methyl-tetrahydro-pyran-3-ol 
• 824-94-2 p-methoxybenzyl chloride 
• 98-88-4 benzoyl chloride 
• 20688-91-9 methyl 3,4-O-isopropylidene-6-O-(p-toluenesulfonyl)-β-D-galactopyranoside 
• 5573-62-6 (ethylthio)trimethylsilane 
• 182167-67-5 Benzoic acid (2R,3R,5R,6R)-6-methoxy-5-(4-methoxy-benzyloxy)-2-methyl-tetrahydro-pyran-3-yl ester 
• 182167-65-3 Methyl 2-O-(p-methoxybenzyl)-3,4-O-sulfonyl-β-D-fucopyranoside 

Downstream Products

• 182167-90-4 Allyl 2-O-benzoyl-3-O-(4-O-benzoyl-3,6-dideoxy-α-D-xylo-hexopyranosyl)-α-D-mannopyranoside 
• 182167-88-0 Allyl 2-O-benzoyl-3-O-[4-O-benzoyl-3,6-dideoxy-2-O-(p-methoxybenzyl)-α-D-xylo-hexopyranosyl]-4,6-di-O-(p-methoxybenzyl)-α-D-mannopyranoside 

Relevant articles and documents

Preparation of disaccharide haptens corresponding to Salmonella serogroups B and D

The properly protected ethyl 1-thio-abequopyranoside 11 and ethyl 1-thio-tyvelo-pyranoside 26 were prepared by a sequence of reactions, the key step of which was the regioselective hydride-mediated ring-opening of the cyclic sulfate function in compounds 8 and 18. Iodonium ion-assisted glycosylation of allyl mannopyranoside 30 with the individual ethyl 3,6-dideoxy-1-thio-D-hexopyranoside donors 11 and 26 furnished, after deprotection, the respective allyl 3-O-(α-D-abequopyranosyl)-α-D-mannopyranoside 1 and allyl 3-O-(α-D-tyvelopyranosyl)-α-D-mannopyranoside 2.