18343-30-1Relevant articles and documents
Selective mono- or dialkoxylation of 2,4,6-trichloro-1,3,5-triazine in solid-liquid phase transfer conditions
Menicagli,Malanga,Peluso
, p. 2153 - 2158 (1994)
In solid-liquid phase transfer conditions, both the primary and the secondary alcohols react cleanly with 2,4, 6-trichloro-1,3,5-triazine to give the corresponding mono or dialkoxy derivatives depending on the reagent molar ratio.
TRIAZINE-2,4-DIONE DERIVATIVE AND MANUFACTURING METHOD THEREFOR
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Paragraph 0021, (2019/07/23)
PROBLEM TO BE SOLVED: To provide a novel triazine-2,4-dione derivative having 2 glycidyl groups as a substituent binding to a nitrogen atom, and further a substituent containing an alkoxy group, and a manufacturing method therefor. SOLUTION: There is provided a triazine-2,4-dione derivative, which is represented by the following formula (1), and is liquid as a state of the material at 25°C, 101.3 kPa. In the formula, R1 represents an alkyl group having 1 to 10 carbon atoms, R2 and R3 represent each independently an alkylene group having 1 to 5 carbon atoms, m and n represent each independently an integer of 0 to 5, and total number of carbon atoms of -(R3O)n(R2O)mR1 group is 1 to 18. SELECTED DRAWING: None COPYRIGHT: (C)2019,JPOandINPIT
KINETICS OF FORMATION OF MONOALKOXY-s-TRIAZINES FROM CYANURIC CHLORIDE.
Marchukov,Koryakov,Lopachenok,V'yunov,Ginak
, p. 574 - 578 (2007/10/02)
2-R-alkoxy-4,6-dichloro-s-triazines (I) are used as intermediates for synthesis of herbicides, and are obtained by reactions of 2,4, 6-trichloro-s-triazine (II) (cyanuric chloride) with various alcohols in aqueous-organic mixtures in presence of hydrogen chloride acceptors. The purpose of this work was to study the quantitive relationships of the main reaction of cyanuric chloride alkoxylation and of the competing reactions of hydrolysis and alkoxylation of compound (I), for optimization of production of monoalkoxy-s-triazines. It is found that the reaction temperature has a significant influence on the yield of 2-(2-R-ethoxy)-4, 6-dichloro-s-triazine; decrease of temperature raises the yield of (I) owing to decrease of the contributions of hydrolysis of compounds (I) and (II) and alkoxylation of (I). The asolute values of the rate constants of hydrolysis (k//3, k//4) and alkoxylation (k//2) decrease more rapidly than k//1 with decrease of temperature. This makes it possible to raise the selectivity of the process by raising the alkali concentration and lowering the reaction temperature.