183994-94-7

Basic information

• Product Name: 4-(broMoMethyl)-N,N-diphenylaniline
• Synonyms: 4-(broMoMethyl)-N,N-diphenylaniline;BenzenaMine, 4-(broMoMethyl)-N,N-diphenyl-;4-(bromomethyl)-N,N-diphenylbenzenamine
• CAS NO: 183994-94-7
• Molecular Formula: C₁₉H₁₆BrN
• Molecular Weight: 338.24104
• Mol File: 183994-94-7.mol
• Article Data: 7

Chemical Properties

• Appearance: /
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• CAS DataBase Reference: 4-(broMoMethyl)-N,N-diphenylaniline(CAS DataBase Reference)
• NIST Chemistry Reference: 4-(broMoMethyl)-N,N-diphenylaniline(183994-94-7)
• EPA Substance Registry System: 4-(broMoMethyl)-N,N-diphenylaniline(183994-94-7)

Safety Data

• Hazardous Substances Data: 183994-94-7(Hazardous Substances Data)

Usage

General Description

4-(Bromomethyl)-N,N-diphenylaniline is a chemical compound with the molecular formula C20H17BrN. It is a substituted diphenylamine derivative that contains a bromomethyl group. 4-(Bromomethyl)-N,N-diphenylaniline is primarily used as a building block in organic synthesis and can serve as a useful intermediate for the production of various pharmaceuticals, agrochemicals, and materials. It may also be employed in research applications to study its reactivity, properties, and potential biological activities. Additionally, it is important to handle this compound with caution as it may pose hazards to human health and the environment.

Upstream product

• 4316-53-4 diphenyl(p-tolyl)amine 
• 25069-40-3 [4-(diphenylamino)phenyl]methanol 
• 603-34-9 N,N-diphenylaminobenzene 
• 4181-05-9 4-(diphenylamino)benzaldehyde 

Downstream Products

• 536992-69-5 4-diphenylaminobenzyltributylphosphonium bromide 
• 332411-27-5 4-[2-(4-diphenylaminophenyl)vinyl]benzaldehyde 
• 536992-56-0 C₂₇H₂₃NO 
• 536992-57-1 C₃₉H₄₉NP⁽¹⁺⁾*Br^(1-) 
• 1229113-74-9 C₂₇H₂₂BrN 
• 1413338-08-5 C₅₇H₅₆N₂Si 
• 1413338-13-2 C₄₀H₃₀N₂ 
• 1413338-15-4 C₄₈H₃₆N₂ 
• 25069-40-3 [4-(diphenylamino)phenyl]methanol 
• 4181-05-9 4-(diphenylamino)benzaldehyde 
• 126150-12-7 Diethyl (4-diphenylamino)benzyl phosphonate 

Relevant articles and documents

Guest Inclusion Modulates Concentration and Persistence of Photogenerated Radicals in Assembled Triphenylamine Macrocycles

Substituted triphenylamine (TPA) radical cations show great potential as oxidants and as spin-containing units in polymer magnets. Their properties can be further tuned by supramolecular assembly. Here, we examine how the properties of photogenerated radical cations, intrinsic to TPA macrocycles, are altered upon their self-assembly into one-dimensional columns. These macrocycles consist of two TPAs and two methylene ureas, which drive the assembly into porous organic materials. Advantageously, upon activation the crystals can undergo guest exchange in a single-crystal-to-single-crystal transformation generating a series of isoskeletal host-guest complexes whose properties can be directly compared. Photoinduced electron transfer, initiated using 365 nm light-emitting diodes, affords radicals at room temperature as observed by electron paramagnetic resonance (EPR) spectroscopy. The line shape of the EPR spectra and the quantity of radicals can be modulated by both polarity and heavy atom inclusion of the encapsulated guest. These photogenerated radicals are persistent, with half-lives between 1 and 7 d and display no degradation upon radical decay. Re-irradiation of the samples can restore the radical concentration back to a similar maximum concentration, a feature that is reproducible over several cycles. EPR simulations of a representative spectrum indicate two species, one containing two N hyperfine interactions and an additional broad signal with no resolvable hyperfine interaction. Intriguingly, TPA analogues without bromine substitution also exhibit similar quantities of photogenerated radicals, suggesting that supramolecular strategies can enable more flexibility in stable TPA radical structures. These studies will help guide the development of new photoactive materials.

Phenylene vinylene platinum(II) acetylides with prodigious two-photon absorption

The linear and nonlinear optical properties of a series of linear and cross-conjugated platinum(II) acetylide complexes that contain extended p-(phenylene vinylene) chromophores are reported. The complexes exhibit very high femtosecond two-photon absorption (2PA) cross section values (σ2 up to 10 000 GM), as measured by nonlinear transmission (NLT) and two-photon excited fluorescence (2PEF) methods. The large 2PA cross sections span a broad range of wavelengths, 570-810 nm, and they overlap with the triplet excited state absorption. Spectral coincidence of high cross section 2PA and triplet absorption is a key feature giving rise to efficient dual-mode optical power limiting (OPL).

Organosilicon-modified charge transporting compound and curable composition containing the compound and having charge transporting ability

An organosilicon-modified charge transporting compound having a structure represented by the following Formula (I): wherein A represents a charge transporting group, Q represents a hydrolytic group or a hydroxyl group, R2represents a monovalent hydrocarbon group or a halogen-substituted monovalent hydrocarbon group having 1 to 15 carbon atoms, n is 1 to 18, m is 1 to 3, and 1 is 1 to 5; and a curable composition containing the organosilicon-modified charge transporting compound and a cure type resin chiefly composed of an organosilicon high polymer.