18406-24-1

Basic information

• Product Name: Silane, triethyl(4-methoxyphenoxy)-
• CAS NO: 18406-24-1
• Molecular Formula: C13H22O2Si
• Molecular Weight: 238.402
• Mol File: 18406-24-1.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: Silane, triethyl(4-methoxyphenoxy)-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, triethyl(4-methoxyphenoxy)-(18406-24-1)
• EPA Substance Registry System: Silane, triethyl(4-methoxyphenoxy)-(18406-24-1)

Safety Data

• Hazardous Substances Data: 18406-24-1(Hazardous Substances Data)

Upstream product

• 994-30-9 triethylsilyl chloride 
• 150-76-5 4-methoxy-phenol 
• 1200-06-2 4-methoxyphenyl acetate 
• 79271-56-0 triethylsilyl trifluoromethyl sulfonate 
• 617-86-7 triethylsilane 
• 18296-01-0 triethylsilyl formate 
• 678187-55-8 diphenyl(triethylsilyl)phosphine 

Downstream Products

• 56892-38-7 1-phenyl-1-((triethylsilyloxy)methyl)ethane 
• 14629-62-0 1-(triethylsiloxy)-2-phenylethane 
• 112473-30-0 triethyl(1-phenylethoxy)silane 
• 42451-53-6 triethyl(1,1-diphenylmethoxy)silane 
• 5290-29-9 triethylsilyl acetate 
• 1018-20-8 triethylsilyl benzoate 
• 1425473-45-5 4-((triethylsilyl)oxy)aniline 
• 929259-42-7 C₁₄H₂₃NO₂Si 

Relevant articles and documents

Use of Silylated Formiates as Hydrosilane Equivalents

The present invention relates to a method for preparing organic compounds of formula (I) by reaction between a silylated formiate of formula (II) and an organic compound in the presence of a catalyst and optionally of an additive. The invention also relates to use of the method for preparing organic compounds of formula (I) for the preparation of reagents for fine chemistry and for heavy chemistry, as well as in the production of vitamins, pharmaceutical products, adhesives, acrylic fibres, synthetic leathers, and pesticides.

Mild synthesis of silyl ethers: Via potassium carbonate catalyzed reactions between alcohols and hydrosilanes

A method has been developed for the silanolysis of alcohols using an abundant and non-corrosive base K2CO3 as a catalyst. Reactions between a variety of alcohols and hydrosilanes generate silyl ethers under mild conditions. The use of hydrosilanes leads to the formation of H2 as the only byproduct thus avoiding the formation of stoichiometric strong acids. The mild conditions lead to a wide scope of possible alcohol substrates and good functional group tolerance. Selective alcohol silanolysis is also observed in the presence of reactive C-H bonds, lending this method for extensive use in protection group chemistry.

Silylation of O-H bonds by catalytic dehydrogenative and decarboxylative coupling of alcohols with silyl formates

The silylation of O-H bonds is a useful methodology in organic synthesis and materials science. While this transformation is commonly achieved by reacting alcohols with reactive chlorosilanes or hydrosilanes, we show herein for the first time that silylformates HCO2SiR3 are efficient silylating agents for alcohols, in the presence of a ruthenium molecular catalyst.