184239-14-3

Basic information

• Product Name: C₁₃H₂₄O₁₀
• Synonyms: C₁₃H₂₄O₁₀
• CAS NO: 184239-14-3
• Molecular Weight: 340.328
• Mol File: 184239-14-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₃H₂₄O₁₀(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₃H₂₄O₁₀(184239-14-3)
• EPA Substance Registry System: C₁₃H₂₄O₁₀(184239-14-3)

Safety Data

• Hazardous Substances Data: 184239-14-3(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 520-26-3 hesperidin 

Relevant articles and documents

Transglycosylation specificity of Acremonium sp. α-rhamnosyl-β- glucosidase and its application to the synthesis of the new fluorogenic substrate 4-methylumbelliferyl-rutinoside

Transglycosylation potential of the fungal diglycosidase α-rhamnosyl-β-glucosidase was explored. The biocatalyst was shown to have broad acceptor specificity toward aliphatic and aromatic alcohols. This feature allowed the synthesis of the diglycoconjugated fluorogenic substrate 4-methylumbelliferyl-rutinoside. The synthesis was performed in one step from the corresponding aglycone, 4-methylumbelliferone, and hesperidin as rutinose donor. 4-Methylumbelliferyl-rutinoside was produced in an agitated reactor using the immobilized biocatalyst with a 16% yield regarding the sugar acceptor. The compound was purified by solvent extraction and silica gel chromatography. MALDI-TOF/TOF data recorded for the [M+Na]+ ions correlated with the theoretical monoisotopic mass (calcd [M+Na]+: 507.44 m/z; obs. [M+Na]+: 507.465 m/z). 4-Methylumbelliferyl-rutinoside differs from 4-methylumbelliferyl-glucoside in the rhamnosyl substitution at the C-6 of glucose, and this property brings about the possibility to explore in nature the occurrence of endo-β-glucosidases by zymographic analysis.