185805-21-4

Basic information

• Product Name: Acrylic acid 2-{[(R)-2-(6-methyl-2,4-dioxo-3,6-diaza-bicyclo[3.1.0]hex-3-yl)-2-phenyl-ethoxy]-diphenyl-silanyloxy}-ethyl ester
• Synonyms: Acrylic acid 2-{[(R)-2-(6-methyl-2,4-dioxo-3,6-diaza-bicyclo[3.1.0]hex-3-yl)-2-phenyl-ethoxy]-diphenyl-silanyloxy}-ethyl ester
• CAS NO: 185805-21-4
• Molecular Weight: 542.663
• Mol File: 185805-21-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Acrylic acid 2-{[(R)-2-(6-methyl-2,4-dioxo-3,6-diaza-bicyclo[3.1.0]hex-3-yl)-2-phenyl-ethoxy]-diphenyl-silanyloxy}-ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Acrylic acid 2-{[(R)-2-(6-methyl-2,4-dioxo-3,6-diaza-bicyclo[3.1.0]hex-3-yl)-2-phenyl-ethoxy]-diphenyl-silanyloxy}-ethyl ester(185805-21-4)
• EPA Substance Registry System: Acrylic acid 2-{[(R)-2-(6-methyl-2,4-dioxo-3,6-diaza-bicyclo[3.1.0]hex-3-yl)-2-phenyl-ethoxy]-diphenyl-silanyloxy}-ethyl ester(185805-21-4)

Safety Data

• Hazardous Substances Data: 185805-21-4(Hazardous Substances Data)

Upstream product

• 80-10-4 diphenylsilyl dichloride 
• 818-61-1 2-hydroxyethyl acrylate 

Downstream Products

• 1026252-26-5 (1R,5S,6R)-3-((R)-2-Hydroxy-1-phenyl-ethyl)-8-methyl-2,4-dioxo-3,8-diaza-bicyclo[3.2.1]octane-6-carboxylic acid methyl ester 
• 185805-22-5 C₃₀H₃₀N₂O₆Si 

Relevant articles and documents

Use of Silicon-Based Tethers to Control Diastereofacial Selectivity in Azomethine Ylide Cycloadditions

A novel approach to controlling the diastereofacial selectivity of intramolecular dipolar cycloadditions of azomethine ylides (cf. 9 → 8) by varying the structure a silicon-based tether is described. A correlation is found between the length of the tether