186772-47-4

Basic information

• Product Name: 1-(tert-butyl)-3-ethynyl-5-[(triisopropylsilyl)ethynyl]benzene
• Synonyms: 1-(tert-butyl)-3-ethynyl-5-[(triisopropylsilyl)ethynyl]benzene
• CAS NO: 186772-47-4
• Molecular Weight: 338.608
• Mol File: 186772-47-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-(tert-butyl)-3-ethynyl-5-[(triisopropylsilyl)ethynyl]benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(tert-butyl)-3-ethynyl-5-[(triisopropylsilyl)ethynyl]benzene(186772-47-4)
• EPA Substance Registry System: 1-(tert-butyl)-3-ethynyl-5-[(triisopropylsilyl)ethynyl]benzene(186772-47-4)

Safety Data

• Hazardous Substances Data: 186772-47-4(Hazardous Substances Data)

Upstream product

• 186772-45-2 1-t-butyl-3-[(triisopropylsilyl)ethynyl]-5-[(trimethylsilyl)ethynyl]benzene 
• 769-92-6 4-tert-Butylaniline 
• 103273-01-4 2-bromo-4-tert-butylaniline 
• 20330-45-4 4-tert-butylacetanilide 
• 91801-97-7 N-(2-bromo-4-tert-butylphenyl)acetamide 
• 144001-06-9 1-(trimethylsilyl)-2-(3-bromo-5-tert-butylphenyl)acetylene 

Downstream Products

• 191983-38-7 1-[3-(tert-Butyl-dimethyl-silanyloxy)-propoxy]-2,5-bis-{3-tert-butyl-5-[(triisopropylsilanyl)-ethynyl]-phenylethynyl}-4-propoxy-benzene 
• 483986-79-4 C₈₇H₉₈O₃Si₂ 
• 483986-78-3 1-tert-butyl-3-[2-(4-ethynylphenyl)ethynyl]-5-(2-triisopropylsilylethynyl)benzene 
• 608527-86-2 6-[3,5-bis(2-{4-[2-(3-tert-butyl-5-ethynyl)phenylethynyl]phenylethynyl})phenoxy]hexyl benzoate 
• 608527-85-1 6-[3,5-bis{2-(4-{2-[3-tert-butyl-5-(2-triisopropylsilylethynyl)]phenylethynyl}phenylethynyl)}phenoxy]hexyl benzoate 
• 1446907-36-3 C₅₄H₇₁NO₂SSi₂ 
• 1446907-35-2 C₄₆H₆₀SSi₂ 
• 1446907-34-1 C₄₈H₆₄O₂SSi₂ 
• 1360170-46-2 C₃₆H₃₄O₂ 
• 1360170-85-9 C₃₆H₃₇NO₄ 
• 1360170-83-7 C₂₂H₂₂O₂ 
• 1360170-43-9 C₅₄H₇₄O₂Si₂ 
• 1360170-80-4 C₃₁H₄₂O₂Si 
• 1360170-51-9 C₆₀H₈₁NO₂Si₂ 

Relevant articles and documents

Synthesis of butadiyne-bridged [4n] metacyclophanes having exo-annular t-butyl groups

Butadiyne-bridged [44]- and [48]metacyclophanes having exo-annular t-butyl groups were prepared by intermolecular Eglinton coupling of the dimeric unit or by intramolecular ring closure of the linear tetramer. Comparison of the 1H and 13C NMR spectra of [44]metacyclophane with those of [48]cyclophane and diphenylbutadiyne revealed its prominent geometrical feature due to deformation of the triple bonds from linearity. The [44]Metacyclophane was converted into [08]thiophenometacyclophane in good yield by treatment with sodium sulfide.