189114-61-2

Basic information

• Product Name: Sliver bis(trifluoromethane sulfonimide)
• Synonyms: Sliver bis(trifluoromethane sulfonimide);Silver bis(trifluoromethanesulfonyl)imide acetonitrile adduct, min. 97%;Silver bis(trifluoroMethanesulfonyl)iMide acetonitrile adduct,97% Ag[(CF3SO2)2N];Silver bis(trifluoromethylsulfonyl)amide;Silver bis(trifluoroMethylsulfonyl)iMide;Silver(I) bis(trifluoroMethanesulfonyl)aMide;Bis(trifluoroMethanesulfonyl)iMidesilver;Silver bis(trifluoroMethanesulfonyl)iMide 97%
• CAS NO: 189114-61-2
• Molecular Formula: Ag*C₂F₆NO₄S₂
• Molecular Weight: 388.0143192
• Product Categories: OTf&NTf series;Ag
• Mol File: 189114-61-2.mol
• Article Data: 11

Chemical Properties

• Melting Point: 249℃
• Appearance: White to orange/Solid
• Storage Temp.: <0°C
• Water Solubility: Soluble in water.
• Sensitive: Moisture & Light Sensitive
• CAS DataBase Reference: Sliver bis(trifluoromethane sulfonimide)(CAS DataBase Reference)
• NIST Chemistry Reference: Sliver bis(trifluoromethane sulfonimide)(189114-61-2)
• EPA Substance Registry System: Sliver bis(trifluoromethane sulfonimide)(189114-61-2)

Safety Data

• Hazard Codes: C
• Statements: 34
• Safety Statements: 26-36/37/39-45
• RIDADR: UN 1759 8/PG 3
• WGK Germany: 3
• HazardClass: 8
• PackingGroup: III
• Hazardous Substances Data: 189114-61-2(Hazardous Substances Data)

Usage

Uses

Different sources of media describe the Uses of 189114-61-2 differently. You can refer to the following data:
1. Gold Catalysts—21st Century'Gold Rush'
2. Silver bis(trifluoromethylsulfonyl)imide is used in the extraction of C5 - C8 linear alfa olefins using its silver salt to form room temperature ionic liquids. Further, it is utilized for the separation of olefins from paraffins.
3. Gold Catalysts — 21st Century ′Gold Rush′

Upstream product

• 82113-65-3 bis(trifluoromethanesulfonyl)amide 
• 90076-65-6 bis(trifluoromethane)sulfonimide lithium 
• 20667-12-3 silver(l) oxide 

Downstream Products

• 1345979-95-4 C₂F₆NO₄S₂^(1-)*C₈H₁₄N₃O⁽¹⁺⁾ 
• 1422393-56-3 [1-ethyl-3-methylmimdazolium][Ag(bis(trifluoromethanesulfonyl)imido)₂] 
• 1422393-58-5 [Ag(1,5-cyclooctadiene)₂]bis(trifluoromethanesulfonyl)imide 
• 1422393-64-3 [Ag(ethylene)₂(bis(trifluoromethanesulfonyl)imido)] 
• 1580889-65-1 C₂₁H₃₈Au₂F₁₂N₂O₈P₂S₄ 
• 1581720-33-3 C₃₄H₃₆INO₂Rh⁽¹⁺⁾*C₂F₆NO₄S₂^(1-) 

Relevant articles and documents

TASK SPECIFIC CHELATING IONIC LIQUIDS FOR REMOVAL OF METAL IONS FROM AQUEOUS SOLUTION VIA LIQUID/LIQUID EXTRACTION AND ELECTROCHEMISTRY

Disclosed are methods of extracting metal ions using ionic liquids (ILs), IL complexes, and mixtures comprising an IL and a metal-chelating group. Also disclosed are IL complexes, and mixtures comprising an IL and a metal-chelating group.

Regioselective Asymmetric Allylic Alkylation Reaction of α -Cyanoacetates Catalyzed by a Heterobimetallic Platina-/Palladacycle

Allylic substitution reactions provide a valuable tool for the functionalization of CH acidic pronucleophiles. Often, control over the stereocenter generated at the nucleophilic reactant is still a challenge. The majority of studies that address this issue employ metal complexes with a low metal oxidation state (e.g. Pd0) to form allyl complexes through oxidative addition. In this article we describe the use of heterobimetallic PtII/PdII complexes, which probably activate the olefinic substrates through an SN2′ pathway. The reaction of α-cyanoacetates delivers linear allylation products with exclusive regioselectivity and high E/Z-selectivity for the new C=C double bond. Although the enantioselectivities attained are moderate, they are significantly higher than with related mono-PdII or -PtII catalysts or the corresponding bis-PdII complex, which indicates cooperation of the different metals. Control experiments suggest simultaneous activation of both reaction partners.

Copper(I) and silver(I) bis(trifluoromethanesulfonyl)imide and their interaction with an arene, diverse olefins, and an NTf2 --based ionic liquid

The chemistry of coinage metal bis(triflyl)imides of technological interest, CuNTf2 and AgNTf2, their synthesis and complexes with excess of comparatively weakly coordinating NTf2- as well as with ether, olefins