19006-71-4Relevant articles and documents
Synthesis of Alkynylthiopyridinium Salts and Their Use as Thioketene Equivalents
Averesch, Kai F. G.,Pesch, Henner,Golz, Christopher,Alcarazo, Manuel
, p. 10472 - 10477 (2019)
A synthetic method has been developed for the preparation of dihalo(pyridinium)sulfuranes and their transformation into alkynylthiopyridinium salts, starting from inexpensive thiopyridones. The reactivity of these salts towards different nucleophiles is evaluated. Most thiols and amines are converted into dithioesters and thioamides, respectively; whereas sterically demanding thiols delivered alkynylthioethers. These results, together with preliminary mechanistic studies reveal that alkynylthiopyridinium salts can be considered synthetic equivalents of unstable thioketenes.
The Conversion of Pyridinium-2-carboxylates into 2-Thioxo-1,2-dihydropyridines (Pyridine-2-thiones)
Katritzky, Alan R.,Faid-Allah, Hassan M.
, p. 149 - 151 (2007/10/02)
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