190968-43-5

Basic information

• Product Name: bis(triphenylphosphino)-η(1)-P-ferrocenyl(tri-tertbutylphenyl)iminophosphinoplatinum(0)
• CAS NO: 190968-43-5
• Molecular Weight: 1195.1
• Mol File: 190968-43-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: bis(triphenylphosphino)-η(1)-P-ferrocenyl(tri-tertbutylphenyl)iminophosphinoplatinum(0)(CAS DataBase Reference)
• NIST Chemistry Reference: bis(triphenylphosphino)-η(1)-P-ferrocenyl(tri-tertbutylphenyl)iminophosphinoplatinum(0)(190968-43-5)
• EPA Substance Registry System: bis(triphenylphosphino)-η(1)-P-ferrocenyl(tri-tertbutylphenyl)iminophosphinoplatinum(0)(190968-43-5)

Safety Data

• Hazardous Substances Data: 190968-43-5(Hazardous Substances Data)

Upstream product

• 12120-15-9 ethylenebis(triphenylphosphine)platinum⁽⁰⁾ 
• 1291-31-2 P,P-dichloroferrocenylphosphine 
• 101455-63-4 lithium N-trimethylsilyl-1-amino-2,4,6-tri-tert-butylbenzene 

Relevant articles and documents

Synthesis and reactivity of P-ferrocenylalkylidenephosphanes and related iminophosphanes and diphosphenes

P-Ferrocenyl-substituted alkylidenephosphanes have been prepared and characterized spectroscopically. Their ready conversion to the corresponding acylphosphanes and 1,2-diacyldiphosphanes, as well as a new type of phosphirene synthesis are presented. The X-ray structure of the tetraferrocenyl-substituted diacyldiphosphane has been investigated. Furthermore, P-ferrocenyl iminophosphanes and their complexation behaviour are described. Diferrocenyldiphosphene, which is known to be unstable, has been stabilized by complexation; this has been confirmed by NMR-spectroscopy and X-ray structure analysis.