191-07-1

Basic information

• Product Name: CORONENE
• Synonyms: Coronene (purity);45070, Coronene (purity);CORONENE, SUBLIMED, 99%;Coronene (refined product of C0386);Coronene solution;1,12:4,5:8,9-Triethenotriphenylene;1,4,7,10,13,16-(1,2,3,4,5,6-Benzenehexyl)-1,3,5,7,9,11,13,15,17-cyclooctadecanonene;Coronene,95%
• CAS NO: 191-07-1
• Molecular Formula: C₂₄H₁₂
• Molecular Weight: 300.35
• EINECS: 205-881-7
• Product Categories: Active Pharmaceutical Ingredients;Electroluminescence;Functional Materials;Alphabetic;C;CO - CZ;Arenes;Building Blocks;Organic Building Blocks;Charge Transport and Photosensitizing MaterialsOrganic Conductors and Photovoltaics: OFET and OPV Materials;ArenesOrganic Electronics and Photonics;OLED and PLED Materials;Organic Semiconductors;p-Type Oligomers;OLED materials,pharm chemical,electronic;strong recommend;Pyrrolidines ,Pyrroles
• Mol File: 191-07-1.mol
• Article Data: 20

Chemical Properties

• Melting Point: 428 °C(lit.)
• Boiling Point: 525 °C(lit.)
• Flash Point: 6 °C
• Appearance: Yellow to greenish/Crystalline Powder
• Density: 1.39
• Vapor Pressure: 1.3E-10mmHg at 25°C
• Refractive Index: 1.4800 (estimate)
• Storage Temp.: 2-8°C
• Solubility: Chloroform (Slightly), Methanol (Slightly)
• Water Solubility: 0.1ug/L(25 oC)
• Stability: Stable. Combustible. Incompatible with strong oxidizing agents.
• Merck: 14,2536
• BRN: 658468
• CAS DataBase Reference: CORONENE(CAS DataBase Reference)
• NIST Chemistry Reference: CORONENE(191-07-1)
• EPA Substance Registry System: CORONENE(191-07-1)

Safety Data

• Hazard Codes: Xn,F
• Statements: 20/21/22-67-65-63-48/20-38-11
• Safety Statements: 36/37-62
• RIDADR: 2811
• WGK Germany: 3
• RTECS: GM5400000
• HazardClass: 6.1(b)
• PackingGroup: III
• Hazardous Substances Data: 191-07-1(Hazardous Substances Data)

Usage

Chemical Properties

yellow to gold fibrous powder

Uses

Different sources of media describe the Uses of 191-07-1 differently. You can refer to the following data:
1. Coronene is a polycyclic aromatic hydrocarbon found in smoked fish and was examined for potential toxic and carcinogenic effects.
2. Ultraviolet phosphor for charge-coupled devices.
3. Used to synthesize MBE-grown layered superconductors.

Definition

ChEBI: A ortho- and peri-fused polycyclic arene that consists of six peri-fused benzene rings.

Carcinogenicity

An initiation–promotion assay in mice gave positive results; a repeated application gave negative results. On the basis of these studies, the working group concluded that these data were inadequate to permit an evaluation of the carcinogenicity of coronene to experimental animals.

Purification Methods

Crystallise coronene from *benzene or toluene, then sublime it in a vacuum. [Beilstein 5 III 2651.]

InChI:InChI=1/C24H12/c1-2-14-5-6-16-9-11-18-12-10-17-8-7-15-4-3-13(1)19-20(14)22(16)24(18)23(17)21(15)19/h1-12H

Synthetic route

9,10-dihydro-9,10-di(penta-1,4-diyn-3-ylidene)anthracene (681164-24-9) → Coronene (191-07-1)

Conditions	Yield
With TpRuPPh3(CH3CN)PF6 In 1,2-dichloro-ethane at 80℃; for 36h;	86%
With ammonium hexafluorophosphate; [dichloro(p-cymene)(triphenylphosphane)ruthenium(II)] In 1,2-dichloro-ethane at 75℃; for 17h;	8 mg

7-benzoperyleneacetaldehyde diethyl acetal → Coronene (191-07-1)

Conditions	Yield
With sulfuric acid In methanol for 0.5h; sonificated;	82%

C32H36O4 → Coronene (191-07-1)

Conditions	Yield
With methanesulfonic acid In dichloromethane at -7 - 20℃; for 1.5h; Reagent/catalyst;	80%

1,5,9-triethynyltriphenylene → Coronene (191-07-1)

Conditions	Yield
With platinum(II) chloride In toluene for 12h; Schlenk technique; Inert atmosphere; Reflux;	57%

propene (187737-37-7) → 8-hydro-phenyl[bc]coronene (107716-56-3) + Coronene (191-07-1)

Conditions	Yield
With KFI molecular sieve catalyst at 475℃; under 750.075 Torr; for 1h; Reagent/catalyst; Temperature; Inert atmosphere;	A 6% B 11%

butan-1-ol (71-36-3) → 8-hydro-phenyl[bc]coronene (107716-56-3) + 8-methyl-8-hydro-phenyl[bc]coronene + 7,8-dimethyl-8-hydro-phenyl[bc]coronene + Coronene (191-07-1)

Conditions	Yield
With DNL-6 molecular sieve microsphere catalyst In water at 475℃; under 750.075 Torr; for 1h; Inert atmosphere;	A 4% B 6% C 6% D 10%

propene (187737-37-7) → 8-methyl-8-hydro-phenyl[bc]coronene + Coronene (191-07-1)

Conditions	Yield
With UZM-9 molecular sieve catalyst at 475℃; under 750.075 Torr; for 1h; Reagent/catalyst; Temperature; Inert atmosphere;	A 6% B 10%

methanol (67-56-1) → 8-hydro-phenyl[bc]coronene (107716-56-3) + 8-methyl-8-hydro-phenyl[bc]coronene + Coronene (191-07-1)

Conditions	Yield
With DNL-6 molecular sieve microsphere catalyst at 500℃; under 750.075 Torr; for 1h; Reagent/catalyst; Temperature; Inert atmosphere;	A 8% B 6% C 6%

propan-1-ol (71-23-8) → 8-hydro-phenyl[bc]coronene (107716-56-3) + 8-methyl-8-hydro-phenyl[bc]coronene + 7,8-dimethyl-8-hydro-phenyl[bc]coronene + Coronene (191-07-1)

Conditions	Yield
With DNL-6 molecular sieve microsphere catalyst In water at 475℃; under 750.075 Torr; for 1h; Inert atmosphere;	A 4% B 6% C 6% D 8%

pentan-1-ol (71-41-0) → 8-hydro-phenyl[bc]coronene (107716-56-3) + 8-methyl-8-hydro-phenyl[bc]coronene + 7,8-dimethyl-8-hydro-phenyl[bc]coronene + Coronene (191-07-1)

Conditions	Yield
With DNL-6 molecular sieve microsphere catalyst In water at 475℃; under 750.075 Torr; for 1h; Inert atmosphere;	A 2% B 6% C 4% D 8%

propene (187737-37-7) → 8-hydro-phenyl[bc]coronene (107716-56-3) + 8-methyl-8-hydro-phenyl[bc]coronene + Coronene (191-07-1)

Conditions	Yield
With RHO molecular sieve catalyst at 525℃; under 750.075 Torr; for 1h; Reagent/catalyst; Temperature; Inert atmosphere;	A 8% B 8% C 6%

methanol (67-56-1) → 8-hydro-phenyl[bc]coronene (107716-56-3) + 8-methyl-8-hydro-phenyl[bc]coronene + 7,8-dimethyl-8-hydro-phenyl[bc]coronene + Coronene (191-07-1)

Conditions	Yield
With DNL-6 molecular sieve microsphere catalyst In water at 475℃; under 750.075 Torr; for 1h; Reagent/catalyst; Temperature; Inert atmosphere;	A 3% B 6% C 4% D 7%

ethene (74-85-1) → Coronene (191-07-1)

Conditions	Yield
With RHO molecular sieve catalyst at 475℃; under 750.075 Torr; for 1h; Inert atmosphere;	6%

[2.2.2]paracyclophane (283-80-7) → Coronene (191-07-1)

Conditions	Yield
With trimethyleneglycol at 380℃;

dibenzo[bc,kl]coronene (190-55-6) → Coronene (191-07-1)

Conditions	Yield
With nitric acid at 220℃; Erhitzen des Reaktionsprodukts mit Natronkalk unter 20 mmHg Wasserstoff-Druck auf 500grad;

1,2-coronene-dione (88889-40-1) → naphth[2',1',8',7';4,10,5]anthra[1,9,8-cdef]chromen-2-one + Coronene (191-07-1)

Conditions	Yield
With lead(II) oxide under 12 Torr; im Luftstrom;

3,4-Coronen-dicarbonsaeure-anhydrid (4444-80-8) → Coronene (191-07-1)

Conditions	Yield
With soda lime at 400℃;

3,4-Coronen-dicarbonsaeure-anhydrid (4444-80-8) → bicoronenyl (56663-32-2) + Coronene (191-07-1)

Conditions	Yield
With potassium hydroxide; nickel at 350℃;

coronene radical cation → Coronene (191-07-1)

Conditions	Yield
With [76]fullerene In dichloromethane Rate constant; Ambient temperature; also with C78;

polyethylene → anthranthrene (191-26-4) + 1-methylene-1H-indene (2471-84-3) + 1-indene (95-13-6) + Coronene (191-07-1)

Conditions	Yield
With air at 800 - 900℃; Oxidation; Formation of xenobiotics;

waste tire → Coronene (191-07-1)

Conditions	Yield
With air at 950℃; Oxidation; Formation of xenobiotics;

pulp and paper-generated biowaste → fluoranthene (206-44-0) + Benzo[ghi]perylene (191-24-2) + Retene (483-65-8) + Coronene (191-07-1)

Conditions	Yield
With air at 976.85℃; Oxidation; Formation of xenobiotics;

9,12-dimethyl-dibenzo[c,g]phenanthrene-3,4-dicarboxylic acid-anhydride (7499-48-1) + water (7732-18-5) + potassium hydroxide → Coronene (191-07-1)

Conditions	Yield
at 320℃; eisernes Gefaess;

9.12-dimethyl-dibenzophenanthrene-carboxylic acid-(3) → Coronene (191-07-1)

Conditions	Yield
With potassium hydroxide; water at 320℃;

9.12-dimethyl-dibenzophenanthrene-dicarboxylic acid-(3.4)-anhydride → Coronene (191-07-1)

Conditions	Yield
With potassium hydroxide; water at 320℃;

[2.2.2]paracyclophane (283-80-7) + PdO → Coronene (191-07-1)

Conditions	Yield
at 380℃;

aluminium trichloride (7446-70-0) + 1,4-di-(2,7)naphtha-cyclohexane (7130-24-7, 61849-91-0, 61849-92-1) + CS2 → Coronene (191-07-1)

Conditions	Yield
Erhitzen des Reaktionsprodukts mit Palladium auf 260grad;

tetracosahydro-coronene (54171-94-7) + selenium → Coronene (191-07-1)

Conditions	Yield
at 360℃; Dehydrierung;

9,12-dimethyl-dibenzo[c,g]phenanthrene-3-carboxylic acid + water (7732-18-5) + sodium hydroxide → Coronene (191-07-1)

Conditions	Yield
at 320℃;

potassium hexafluorophosphate (17084-13-8) + cis-[Pt(II)(PEt)3(trifluoromethane-sulfonate)2] (165336-82-3) + 6Pt(2+)*12P(C2H5)3*4C3N3(C5H4N)3*12CF3SO3(1-)*2CH3COCH3=Pt6(P(C2H5)3)12(C3N3(C5H4N)3)4(CF3SO3)12*2CH3COCH3 + fumaric acid disodium salt (17013-01-3) + Coronene (191-07-1) → 6Pt(2+)*12P(C2H5)3*2C3N3(C5H4N)3*2C2H2(COO)2(2-)*C24H12*8PF6(1-)=Pt6(P(C2H5)3)12(C3N3(C5H4N)3)2(C4H2O4)2(PF6)8*C24H12

Conditions	Yield
In [(2)H6]acetone; water; acetone to acetone soln. of triazine complex were added aq. soln. of carboxylate,coronene and aq. suspn. of platinum complex, sealed, immersed at 70°C for 1 h, solvent was removed, dried in vac., acetone-d6 was added, heated at 70°C for 1 h, aq. KPF6; elem. anal.;	96%

C108H100Ir4N16(8+)*8CF3O3S(1-) + Coronene (191-07-1) → C108H100Ir4N16(8+)*8CF3O3S(1-)*2C24H12

Conditions	Yield
In methanol at 20℃; for 24h;	95.5%

C108H100N16Rh4(8+)*8CF3O3S(1-) + Coronene (191-07-1) → C108H100N16Rh4(8+)*8CF3O3S(1-)*2C24H12

Conditions	Yield
In methanol at 20℃; for 24h;	94.5%

C128H152Cl4Cu4N4O24Rh4(4+)*4CF3O3S(1-) + Coronene (191-07-1) → C128H152Cl4Cu4N4O24Rh4(4+)*4CF3O3S(1-)*C24H12

Conditions	Yield
In methanol at 20℃; for 6h; Inert atmosphere; Schlenk technique;	93.8%

Coronene (191-07-1) → 1,2,3,4,5,6,7,8,9,10,11,12-dodecakischlorocoronene (94227-23-3)

Conditions	Yield
With aluminum (III) chloride; Iodine monochloride In tetrachloromethane at 81℃; for 48h; Inert atmosphere; Schlenk technique;	93%
With disulfur dichloride; aluminium trichloride; sulfuryl dichloride for 28h; Heating;	90%

4,4'-bipyridine (553-26-4) + dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer + [Ag2(1,3-di(3-pyridyl)propane-1,3-dionato)2][OTf]2 + silver trifluoromethanesulfonate (2923-28-6) + Coronene (191-07-1) → C112H112Ag4N12O8Rh4(8+)*8CF3O3S(1-)*2C24H12

Conditions	Yield
Stage #1: dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; silver trifluoromethanesulfonate In methanol at 20℃; for 6h; Darkness; Stage #2: 4,4'-bipyridine; [Ag2(1,3-di(3-pyridyl)propane-1,3-dionato)2][OTf]2; Coronene at 20℃; for 24h;	89.6%

[Cp*Rh]2(4,4’-bis(dipyrromethane-5-yl)biphenyl)Cl2 + [Cu2(bddp)2] + silver trifluoromethanesulfonate (2923-28-6) + N,N′-dimethyl-1,4,5,8-naphthalenetetracarboxylic diimide (20958-66-1) + Coronene (191-07-1) → 2C30H20N4(2-)*4C10H15(1-)*4C19H23NO4(2-)*4Cu(2+)*4Rh(3+)*4CF3O3S(1-)*2C24H12*2C16H10N2O4

Conditions	Yield
Stage #1: [Cp*Rh]2(4,4’-bis(dipyrromethane-5-yl)biphenyl)Cl2; silver trifluoromethanesulfonate In methanol at 20℃; for 6h; Darkness; Stage #2: [Cu2(bddp)2] for 12h; Stage #3: N,N′-dimethyl-1,4,5,8-naphthalenetetracarboxylic diimide; Coronene at 20℃; for 6h;	81.5%

2,4,6-tri(4-pyridyl)-1,3,5-triazine (42333-78-8) + dichloro(μ-[6,11-di(hydroxy-κO)naphthacene-5,12-dionato(2-)-κO5:κO12])bis[(1,2,3,4,5,6-η)-1-methyl-4-(1-methylethyl)benzene]diruthenium + silver trifluoromethanesulfonate (2923-28-6) + Coronene (191-07-1) → coronene.cntnd.[Ru2(p-cymene)2Cl2(6,11-dioxo-6,11-dihydronaphthacene-5,12-diolato)]3(2,4,6-tris(4-pyridyl)-1,3,5-triazine)(SO3CF3

Conditions	Yield
In methanol to mixt. of Ru complex and Ag triflate in MeOH added triazine deriv. andcoronene; mixt. stirred at reflux for 24 h; filtered, solvent removed, residue dissolved in CH2Cl2, Et2O added for pptn.. solid filtered, dried under vac.; elem. anal.;	81%

1,3,5-tris{2-(pyridin-4-yl)-vinyl}benzene (157131-39-0) + (η6-p-cymRu)2(μ4-5,8-dihydroxy-1,4-naphthoquinone)Cl2 + silver trifluoromethanesulfonate (2923-28-6) + Coronene (191-07-1) → [coronene*Ru6(p-cymene)6(1,3,5-tris{2-(pyridin-4-yl)-vinyl}benzene)2(μ-5,8-dioxido-1,4-naphthoquinonato)3][trifluoromethanesulfonate]6

Conditions	Yield
In methanol for 24h; Reflux;	81%

Dichloromethyl methyl ether (4885-02-3) + Coronene (191-07-1) → 1-coronenecarboxaldehyde (22138-86-9)

Conditions	Yield
With tin(IV) chloride In dichloromethane; 1,2-dichloro-ethane at 20℃; for 19h;	76%

2,4,6-tri(4-pyridyl)-1,3,5-triazine (42333-78-8) + silever triflate + C30H41Cl2N2O2Ru2 + Coronene (191-07-1) → C24H12*C126H147N18O6Ru6(6+)*6CF3O3S(1-)

Conditions	Yield
Stage #1: silever triflate; C30H41Cl2N2O2Ru2 With air In dichloromethane at 20℃; for 2h; Stage #2: 2,4,6-tri(4-pyridyl)-1,3,5-triazine; Coronene In dichloromethane at 20℃; for 48h;	75%

2,5-dimethoxy-7,7,8,8-tetracyano-p-quinodimethane (21003-99-6) + Coronene (191-07-1) → (coronene)[(MeO)2TCNQ]

Conditions	Yield
In dichloromethane	72%

2,4,6-tri(4-pyridyl)-1,3,5-triazine (42333-78-8) + [Ru2(η6-p-cymene)2(C6H2O4)Cl2] (1039768-31-4) + silver trifluoromethanesulfonate (2923-28-6) + Coronene (191-07-1) → coronene*[Ru6(p-cymene)6(2,4,6-tris(4-pyridyl)-1,3,5-triazine)2(2,5-dioxy-1,4-benzoquinonato)3](O3SCF3)6

Conditions	Yield
In methanol byproducts: AgCl; a mixt. of complex and Ag-salt in methanol was stirred at room temp. for2 h, filtered, triazine-compound and aromatic molecule were added, the mixt. was stirred at room temp. for 24 h; the solvent was removed under vac., the residue was taken up in CH2Cl2, filtered, concd., diethyl ether was added; elem. anal.;	70%

1,3,5-tris{2-(pyridin-4-yl)-vinyl}benzene (157131-39-0) + [Ru2(p-cymene)2(μ-9,10-dioxido-1,4-anthraquinonato)Cl2] (201941-87-9) + silver trifluoromethanesulfonate (2923-28-6) + Coronene (191-07-1) → [coronene*Ru6(p-cymene)6(1,3,5-tris{2-(pyridin-4-yl)-vinyl}benzene)2(μ-9,10-dioxido-1,4-anthraquinonato)3][trifluoromethanesulfonate]6

Conditions	Yield
In methanol for 24h; Reflux;	66%

2,3,5,6-tetrafluoro-7,7',8,8'-tetracyanoquinodimethane (29261-33-4) + Coronene (191-07-1) → (coronene)(F4TCNQ)

Conditions	Yield
In dichloromethane	66%

18-crown-6 ether (17455-13-9) + rubidium + Coronene (191-07-1) → [Rb(18-crown-6)][coronene]

Conditions	Yield
In tetrahydrofuran for 8h; Inert atmosphere; Schlenk technique;	65%

7,7',8,8'-tetracyanoquinodimethane (1518-16-7) + Coronene (191-07-1) → (coronene)3*TCNQ

Conditions	Yield
In benzene for 12h;	61%

1,2-dimethoxyethane (110-71-4) + Coronene (191-07-1) → coronene

Conditions	Yield
Stage #1: 1,2-dimethoxyethane; Coronene With sodium at 20℃; for 8h; Inert atmosphere; Stage #2: With Coarannulen In 1,2-dimethoxyethane; hexane at 10℃; for 48h; Inert atmosphere;	60%

6C66H52N4Ni*4Fe(2+)*8C2F6NO4S2(1-) + Coronene (191-07-1) → 6C66H52N4Ni*4Fe(2+)*8C2F6NO4S2(1-)*2C24H12

Conditions	Yield
In [D3]acetonitrile at 20℃; for 1h;	60%

Upstream product

• 283-80-7 [2.2.2]paracyclophane 
• 190-55-6 dibenzo[bc,kl]coronene 
• 4444-80-8 3,4-Coronen-dicarbonsaeure-anhydrid 
• 7446-70-0 aluminium trichloride 
• 7130-24-7 1,4-di-(2,7)naphtha-cyclohexane 
• 54171-94-7 tetracosahydro-coronene 
• 7499-48-1 9,12-dimethyl-dibenzo[c,g]phenanthrene-3,4-dicarboxylic acid-anhydride 
• 7732-18-5 water 
• 88889-40-1 1,2-coronene-dione 
• 74-85-1 ethene 
• 187737-37-7 propene 
• 71-41-0 pentan-1-ol 
• 71-36-3 butan-1-ol 
• 71-23-8 propan-1-ol 

Downstream Products

• 121499-59-0 2-coronenecarbonyl-benzoic acid 
• 100211-88-9 coronenyl-phenyl ketone 
• 54171-94-7 tetracosahydro-coronene 
• 125379-41-1 Δ^12b,12d,12f-octadecahydro-coronene 
• 98570-53-7 benzo<1,2,3-bc:4,5,6-b'c'>dicoronene 
• 81316-84-9 nitro-coronene 
• 113845-11-7 1,2,5,6,9,10-hexahydro-coronene 
• 125413-07-2 1,2,5,6-Tetrahydro-coronene 
• 125379-40-0 1,2,2a,4a,5,6,9,10,12c,12d-Decahydro-coronene 
• 98570-54-8 Cyclopenta<1,2-a:3,4,5-b'c'>dicoronene 
• 94227-23-3 1,2,3,4,5,6,7,8,9,10,11,12-dodecakischlorocoronene 
• 74-86-2 acetylene 
• 1246086-42-9 C₆₁H₅₉NO₃S 

Relevant articles and documents

Gram scale synthesis of benzo[ghi]perylene and coronene

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Method for preparing coronene compound from non-cyclic olefin

The invention relates to a method for preparing a coronene compound from non-cyclic olefin. The method is characterized by comprising the following steps of: putting a reaction raw material into a reactor, and carrying out contact reaction with a catalyst containing an activated silicon-aluminum molecular sieve to obtain the coronene compound; wherein the reaction raw material comprises non-cyclicolefin. The method is mild in preparation condition, easy to operate and simple in process; the adopted raw material is low in cost and easy to obtain, therefore the method is suitable for large-scale production.

ORGANIC COMPOUND, THREE-DIMENSIONAL ORGANIC FRAMEWORK FORMED BY USING ORGANIC COMPOUND, SEPARATION SIEVE AND OPTICAL LAYER, WHICH COMPRISE ORGANIC FRAMEWORK, AND OPTICAL DEVICE COMPRISING OPTICAL LAYER AS OPTICAL AMPLIFICATION LAYER

An organic compound, a three-dimensional organic structure formed by using the organic compound, a separation sieve and an optical layer having the organic structure, and an optical device having the optical layer as an optical amplification layer are provided. The organic structure includes a plurality of organic molecules self-assembled by non-covalent bonding. Each of the unit organic molecules has an aromatic ring, a first pair of substituents being connected to immediately adjacent positions of substitutable positions of the aromatic ring, and a second pair of substituents being connected to immediately adjacent positions of remaining substitutable positions of the aromatic ring. The unit organic molecules are self-assembled by van der Waals interaction, London dispersion interaction or hydrogen bonding between the first and the second pairs of the substituents and by pi-pi interactions between the aromatic rings.

1, 5, 9-trisubstituted coronene compound and synthesis method thereof

The present invention relates to a 1, 5, 9-trisubstituted coronene compound and a synthesis method thereof. The structural formula of the compound is shown in img file = 'dest _ path _ image 001. TIF 'wi = '109 'he = '108', wherein R represents H, C1-C18 alkyl, phenyl, 4-methylphenyl, 4-methoxy phenyl, benzyl, cyclohexyl, 4-trifluoromethylphenyl, thiophene, furan and the like. According to the technical scheme of the invention, the easily prepared 1, 5, 9-triamido triphenylene is subjected to diazotization and halogenation reaction to obtain the tri-halogenated triphenylene. After that, the tri-halogenated triphenylene is subjected to Sonogashira reaction with various alkynes to generate atriyne-triphenylene compounds. Finally, through the metal-catalyzed reaction and the cyclization reaction under the effect of an organic base, various 1, 5, 9-trisubstituted coronene compounds, novel in structure, can be obtained. According to the technical scheme of the invention, raw materials are easy for mass preparation. Meanwhile, the synthesis step is relatively short and the operation is convenient. The obtained trisubstituted coronene compound is good in thermal stability and chemical stability, and the trisubstituted coronene emits the relatively strong fluorescence within the range of 420-550 nm according to the fluorescence emission spectrum of the trisubstituted coronene compound. Therefore, the trisubstituted coronene is an excellent fluorescent material for preparing UV ultraviolet charge-coupled devices (UV-CCD) and organic light-emitting diodes (OLEDs), and has a wide application prospect in the field of electronic materials.