191231-64-8

Basic information

• Product Name: C₆H₄(C₄C₆H₄C₂Si(CH(CH₃)2)3)2
• Synonyms: C₆H₄(C₄C₆H₄C₂Si(CH(CH₃)2)3)2
• CAS NO: 191231-64-8
• Molecular Weight: 687.128
• Mol File: 191231-64-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: C₆H₄(C₄C₆H₄C₂Si(CH(CH₃)2)3)2(CAS DataBase Reference)
• NIST Chemistry Reference: C₆H₄(C₄C₆H₄C₂Si(CH(CH₃)2)3)2(191231-64-8)
• EPA Substance Registry System: C₆H₄(C₄C₆H₄C₂Si(CH(CH₃)2)3)2(191231-64-8)

Safety Data

• Hazardous Substances Data: 191231-64-8(Hazardous Substances Data)

Upstream product

• 351389-18-9 1-bromo-2-(4-trimethylsilyl-1,3-butadiynyl)benzene 
• 615-42-9 1,2-Diiodobenzene 
• 191231-69-3 2-[(triisopropylsilyl)ethynyl]-1-[4-(trimethylsilyl)-1,3-butadiynyl]benzene 
• 583-55-1 1-Bromo-2-iodobenzene 

Relevant articles and documents

A versatile synthetic route to dehydrobenzoannulenes via in situ generation of reactive alkynes

This paper outlines the development of a protocol that allows in situ generation of unstable alkynes under Pd-catalyzed cross-coupling conditions. Cu-mediated intramolecular cyclization of the resultant α,ω-polyynes provides dehydrobenzoannulenes as singular species, in very good overall yields, and in a variety of topologies that are inaccessible by traditional routes or previously available in low yield only. In addition, we will discuss the solid-state structure and reactivity of these macrocycles, as well as the ability of the planar dehydrobenzoannulenes to support weak induced ring currents.

Carbon Networks Based on Dehydrobenoannulenes: Synthesis of Graphdiyne Substructures

Keywords: alkynes; annulenes; aromaticity; carbon allotropes