192461-84-0

Basic information

• Product Name: (S)-N-(diphenylphosphinyl)-1,2,3,4-tetrahydro-1-naphthylidene
• Synonyms: (S)-N-(diphenylphosphinyl)-1,2,3,4-tetrahydro-1-naphthylidene
• CAS NO: 192461-84-0
• Molecular Weight: 347.397
• Mol File: 192461-84-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (S)-N-(diphenylphosphinyl)-1,2,3,4-tetrahydro-1-naphthylidene(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-N-(diphenylphosphinyl)-1,2,3,4-tetrahydro-1-naphthylidene(192461-84-0)
• EPA Substance Registry System: (S)-N-(diphenylphosphinyl)-1,2,3,4-tetrahydro-1-naphthylidene(192461-84-0)

Safety Data

• Hazardous Substances Data: 192461-84-0(Hazardous Substances Data)

Upstream product

• 192461-79-3 N-[(1E)-3,4-dihydronaphthalen-1(2H)-ylidene]-P,P-diphenylphosphinic amide 

Downstream Products

• 23357-52-0 (S)-1,2,3,4-tetrahydronapht-1-yl-amine 

Relevant articles and documents

Zinc-catalyzed enantioselective hydrosilylation of imines

The highly enantioselective reduction of imines is achieved by employing chiral Zn/diamine catalysts. This new catalytic protocol offers attractive features such as use of a non-precious metal and an inexpensive silane, easy modification of chiral diamine

Enantioselective borohydride reduction of N-diphenylphosphinyl imines using optically active cobalt(II) complex catalysts

The enantioselective borohydride reduction using optically active cobalt(II) complex catalysts was successfully applied to various aryl N-diphenylphosphinyl imines, and the corresponding reduced products were obtained in good yields with high enantiomeric excesses (up to 99% ee). The optically active primary amines were obtained by the successive hydrolysis under mild conditions.