19264-71-2Relevant articles and documents
Molecular Engineering through Control of Structural Deformation for Highly Efficient Ultralong Organic Phosphorescence
Yin, Zheng,Gu, Mingxing,Ma, Huili,Jiang, Xueyan,Zhi, Jiahuan,Wang, Yafei,Yang, Huifang,Zhu, Weiguo,An, Zhongfu
supporting information, p. 2058 - 2063 (2020/11/30)
It is an enormous challenge to achieve highly efficient organic room-temperature phosphorescence (RTP) with a long lifetime. We demonstrate that, by bridging the carbazole and halogenated phenyl ring with a methylene linker, RTP phosphors CzBX (X=Cl, Br) present high phosphorescence efficiency (ΦPh). A ΦPh up to 38 % was obtained for CzBBr with a lifetime of 220 ms, which is much higher than that of compounds CzPX (X=Cl, Br) with a C?N bond as a linker (ΦPh3 methylene linkers restrain the nonradiative decay channel, leading to the high phosphorescence efficiency in CzBBr. This research paves a new road toward highly efficient and long-lived RTP materials with potential applications in anti-counterfeiting or data encryption.
Preparation method of 4-(9H-carbazol-9-yl)phenylboronic acid
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Paragraph 0005; 0021-0023; 0029-0031, (2021/11/06)
The invention relates to a preparation method of 4-(9H-carbazol-9-yl)phenylboronic acid, belonging to the technical field of organic synthesis. The preparation method comprises the following steps: with carbazole as an initial raw material, subjecting carbazole to reacting with 4-chlorobromobenzene to generate 9-(4-chlorphenyl)-9H-carbazole; and then condensing 9-(4-chlorphenyl)-9H-carbazole with triethyl borate, and carrying out hydrolyzing to generate the 4-(9H-carbazol-9-yl)phenylboronic acid. According to the method, n-butyllithium is not used in the process of preparing the 4-(9H-carbazol-9-yl)phenylboronic acid, so an ultralow-temperature reaction is avoided, and all the reactions are carried out under mild conditions; and compared with an existing synthesis process, the method is more suitable for industrial production.
Novel compound and organic light emitting device comprising the same
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Paragraph 0216-0218, (2021/08/17)
The present invention provides a novel compound and an organic light emitting device using the same. The present invention provides a compound represented by chemical formula 1. The compound represented by chemical formula 1 can be used as a material for an organic layer of the organic light emitting device, and can improve efficiency, lower driving voltage, and/or improve lifespan characteristics in the organic light emitting device.