194805-72-6Relevant articles and documents
Preparation of conjugated dienoates with Bestmann ylide: Towards the synthesis of zampanolide and dactylolide using a facile linchpin approach
Wang, Jingjing,Ting, Samuel Z. Y.,Harvey, Joanne E.
supporting information, p. 1815 - 1822 (2016/04/10)
Bestmann ylide [(triphenylphosphoranylidene)ketene] acts as a chemical linchpin that links nucleophilic entities, such as alcohols or amines, with carbonyl moieties to produce unsaturated esters and amides, respectively. In this work, the formation of α,β
Catalytic synthesis of enantiopure mixed diacylglycerols-synthesis of a major M. tuberculosis phospholipid and platelet activating factor
Fodran, Peter,Minnaard, Adriaan J.
supporting information, p. 6919 - 6928 (2013/10/08)
An efficient catalytic one-pot synthesis of TBDMS-protected diacylglycerols has been developed, starting from enantiopure glycidol. Subsequent migration-free deprotection leads to stereo- and regiochemically pure diacylglycerols. This novel strategy has been applied to the synthesis of a major Mycobacterium tuberculosis phospholipid, its desmethyl analogue, and platelet activating factor.
Phosphonyl radical addition to enol ethers. The stereoselective synthesis of cyclic ethers
Jessop, Christopher M.,Parsons, Andrew F.,Routledge, Anne,Irvine, Derek J.
, p. 5095 - 5098 (2007/10/03)
Addition of diethyl phosphite or diethyl thiophosphite to enol ethers, in the presence of a radical initiator, results in the regioselective synthesis of organophosphonate or phosphonothioate derivatives, respectively, under mild conditions. This method c
